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An Experimentally Derived Model for Stereoselectivity in the Aerobic Oxidative Kinetic Resolution of Secondary Alcohols by (Sparteine)PdCl_2

Trend, Raissa M. and Stoltz, Brian M. (2004) An Experimentally Derived Model for Stereoselectivity in the Aerobic Oxidative Kinetic Resolution of Secondary Alcohols by (Sparteine)PdCl_2. Journal of the American Chemical Society, 126 (14). pp. 4482-4483. ISSN 0002-7863. doi:10.1021/ja039551q. https://resolver.caltech.edu/CaltechAUTHORS:20170216-072248452

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Abstract

A model for asymmetric induction in palladium-catalyzed aerobic oxidative kinetic resolution is described. The model is based on coordination complexes and general reactivity trends of the parent (sp)PdCl2 catalyst. The first example of a nonracemic chiral palladium alkoxide complex is presented, and exhibits the subtle steric influences of the C1symmetric ligand sparteine.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja039551qDOIArticle
http://pubs.acs.org/doi/suppl/10.1021/ja039551qPublisherSupporting Information
ORCID:
AuthorORCID
Stoltz, Brian M.0000-0001-9837-1528
Additional Information:© 2004 American Chemical Society. Received 11 November 2003. Published online 18 March 2004. Published in print 1 April 2004. We are grateful to Caltech and the A. P. Sloan Foundation for financial support. We are indebted to Dr. M. W. Day and Mr. L. M. Henling for X-ray crystallographic expertise as well as to Professors J. E. Bercaw, R. H. Grubbs, H. B. Gray, and J. C. Peters and their groups for assistance and helpful discussions.
Funders:
Funding AgencyGrant Number
CaltechUNSPECIFIED
Alfred P. Sloan FoundationUNSPECIFIED
Issue or Number:14
DOI:10.1021/ja039551q
Record Number:CaltechAUTHORS:20170216-072248452
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20170216-072248452
Official Citation:An Experimentally Derived Model for Stereoselectivity in the Aerobic Oxidative Kinetic Resolution of Secondary Alcohols by (Sparteine)PdCl2 Raissa M. Trend and Brian M. Stoltz Journal of the American Chemical Society 2004 126 (14), 4482-4483 DOI: 10.1021/ja039551q
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:74359
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:16 Feb 2017 16:01
Last Modified:11 Nov 2021 05:26

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