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Electronic structures and photophysics of d^8-d^8 complexes

Gray, Harry B. and Záliš, Stanislav and Vlček, Antonín (2017) Electronic structures and photophysics of d^8-d^8 complexes. Coordination Chemistry Reviews, 345 . pp. 297-317. ISSN 0010-8545. doi:10.1016/j.ccr.2017.01.008.

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Research on d^8-d^8 complexes is being actively pursued, owing, in part, to newly developed time-resolved optical, IR, and X-ray methods that directly interrogate bonding changes upon excitation. Our review covers work on the ground- and electronic excited states, as well as the oxidized and reduced forms, of these complexes. Recent experimental and theoretical results add a new chapter to the rich history of d^8-d^8 spectroscopic and chemical behavior.

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Gray, Harry B.0000-0002-7937-7876
Additional Information:© 2017 Elsevier B.V. Received 29 October 2016, Revised 17 January 2017, Accepted 18 January 2017, Available online 21 January 2017. We thank our colleagues for interesting discussions of d^8-d^8 chemistry as well as sharing some (yet) unpublished data, most especially Majed Chergui, Ivano Tavernelli, Roberto Moni, and Gloria Capano (EFPFL, Switzerland); and Jay Winkler, Bryan Hunter, and Yan-Choi Lam (Caltech). This work was supported by the NSF CCI Solar Fuels Program (CHE-1305124), the Arnold and Mabel Beckman Foundation, the Ministry of Education of the Czech Republic - grant LH13015, and the COST Action CM1405. Dedicated to Barry Lever, consummate scholar and treasured friend, in recognition of his deep and lasting contributions to coordination chemistry.
Group:CCI Solar Fuels
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Arnold and Mabel Beckman FoundationUNSPECIFIED
Ministry of Education (Czech Republic)LH13015
COST ActionCM1405
Record Number:CaltechAUTHORS:20170221-084923487
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Official Citation:Harry B. Gray, Stanislav Záliš, Antonín Vlček, Electronic structures and photophysics of d8-d8 complexes, Coordination Chemistry Reviews, Volume 345, 15 August 2017, Pages 297-317, ISSN 0010-8545, (
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:74420
Deposited By: Ruth Sustaita
Deposited On:21 Feb 2017 17:30
Last Modified:11 Nov 2021 05:27

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