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A Convergent and Enantioselective Synthesis of (+)-Amurensinine via Selective C−H and C−C Bond Insertion Reactions

Tambar, Uttam K. and Ebner, David C. and Stoltz, Brian M. (2006) A Convergent and Enantioselective Synthesis of (+)-Amurensinine via Selective C−H and C−C Bond Insertion Reactions. Journal of the American Chemical Society, 128 (36). pp. 11752-11753. ISSN 0002-7863. PMCID PMC2529249. https://resolver.caltech.edu/CaltechAUTHORS:20170221-152140812

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Abstract

A convergent and enantioselective synthesis of the natural product amurensinine is described. The synthetic strategy takes advantage of mild and selective C−H and C−C bond insertion reactions, in addition to the palladium-catalyzed aerobic oxidative kinetic resolution recently developed in these laboratories.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja0651815DOIArticle
http://pubs.acs.org/doi/suppl/10.1021/ja0651815PublisherSupporting Information
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2529249/PubMed CentralArticle
ORCID:
AuthorORCID
Stoltz, Brian M.0000-0001-9837-1528
Additional Information:© 2006 American Chemical Society. Received 20 July 2006. Published online 17 August 2006. Published in print 1 September 2006. The authors are grateful to the NIH-NIGMS (R01 GM65961-01), NDSEG (predoctoral fellowships to U.K.T. and D.C.E.), NSF (predoctoral fellowship to D.C.E.), A. P. Sloan Foundation, Research Corporation, Bristol-Myers Squibb, Amgen, Merck, Pfizer, Novartis, Lilly, Roche, Abbott, AstraZeneca, and Caltech for financial support.
Funders:
Funding AgencyGrant Number
NIHR01GM65961-01
National Defense Science and Engineering Graduate (NDSEG) FellowshipUNSPECIFIED
NSF Predoctoral FellowshipUNSPECIFIED
Alfred P. Sloan FoundationUNSPECIFIED
Research CorporationUNSPECIFIED
Bristol-Myers SquibbUNSPECIFIED
AmgenUNSPECIFIED
MerckUNSPECIFIED
PfizerUNSPECIFIED
NovartisUNSPECIFIED
LillyUNSPECIFIED
RocheUNSPECIFIED
AbbottUNSPECIFIED
AstraZenecaUNSPECIFIED
CaltechUNSPECIFIED
Issue or Number:36
PubMed Central ID:PMC2529249
Record Number:CaltechAUTHORS:20170221-152140812
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20170221-152140812
Official Citation:A Convergent and Enantioselective Synthesis of (+)-Amurensinine via Selective C−H and C−C Bond Insertion Reactions Uttam K. Tambar, David C. Ebner, and Brian M. Stoltz Journal of the American Chemical Society 2006 128 (36), 11752-11753 DOI: 10.1021/ja0651815
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:74438
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:22 Feb 2017 00:00
Last Modified:15 Jun 2020 20:05

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