Marinescu, Smaranda C. and Nishimata, Toyoki and Mohr, Justin T. and Stoltz, Brian M. (2008) Homogeneous Pd-Catalyzed Enantioselective Decarboxylative Protonation. Organic Letters, 10 (6). pp. 1039-1042. ISSN 1523-7060. PMCID PMC2966305. doi:10.1021/ol702821j. https://resolver.caltech.edu/CaltechAUTHORS:20170221-162726154
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Abstract
General homogeneous conditions for the palladium-catalyzed synthesis of carbonyl compounds with tertiary carbon stereocenters at the α-position are reported. The highly reactive catalyst tolerates a variety of substrate substitution and functionality, and generates enantioenriched cyclic ketones from racemic allyl β-ketoester starting materials.
Item Type: | Article | ||||||||||||
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Additional Information: | © 2008 American Chemical Society. Received November 21, 2007. Publication Date (Web): February 28, 2008. We thank Sankyo Co., Ltd. (financial support of T.N.), Eli Lilly (predoctoral fellowship to J.T.M.), Amgen, and Bristol-Myers Squibb for generous funding. | ||||||||||||
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Issue or Number: | 6 | ||||||||||||
PubMed Central ID: | PMC2966305 | ||||||||||||
DOI: | 10.1021/ol702821j | ||||||||||||
Record Number: | CaltechAUTHORS:20170221-162726154 | ||||||||||||
Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20170221-162726154 | ||||||||||||
Official Citation: | Homogeneous Pd-Catalyzed Enantioselective Decarboxylative Protonation Smaranda C. Marinescu, Toyoki Nishimata, Justin T. Mohr, and Brian M. Stoltz Organic Letters 2008 10 (6), 1039-1042 DOI: 10.1021/ol702821j | ||||||||||||
Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||||
ID Code: | 74444 | ||||||||||||
Collection: | CaltechAUTHORS | ||||||||||||
Deposited By: | George Porter | ||||||||||||
Deposited On: | 22 Feb 2017 15:59 | ||||||||||||
Last Modified: | 11 Nov 2021 05:27 |
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