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Palladium-Catalyzed Enantioselective Oxidation of Alcohols: A Dramatic Rate Acceleration by Cs_2CO_3/t-BuOH

Bagdanoff, Jeffrey T. and Ferreira, Eric M. and Stoltz, Brian M. (2003) Palladium-Catalyzed Enantioselective Oxidation of Alcohols: A Dramatic Rate Acceleration by Cs_2CO_3/t-BuOH. Organic Letters, 5 (6). pp. 835-837. ISSN 1523-7060. doi:10.1021/ol027463p.

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The addition of Cs_2CO_3 and t-BuOH provides a dramatic rate acceleration in the palladium-catalyzed aerobic oxidative kinetic resolution of secondary alcohols while maintaining the selectivity of the process.

Item Type:Article
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Stoltz, Brian M.0000-0001-9837-1528
Additional Information:© 2003 American Chemical Society. Received 13 December 2002. Published online 14 February 2003. Published in print 1 March 2003. We wish to thank the NIH-NIGMS (R01 GM65961-01), the California Institute of Technology, the Camille and Henry Dreyfus Foundation (New Faculty Award to B.M.S.), the Merck Research Laboratories, Research Corporation, The University of California TRDRP (predoctoral fellowship to J.T.B.), the National Science Foundation (predoctoral fellowship to E.M.F.), GlaxoSmithKline, and Abbott Laboratories for generous financial support.
Funding AgencyGrant Number
Camille and Henry Dreyfus FoundationUNSPECIFIED
Merck Research LaboratoriesUNSPECIFIED
Research CorporationUNSPECIFIED
California Tobacco-Related Disease Research ProgramUNSPECIFIED
NSF Predoctoral FellowshipUNSPECIFIED
Abbott LaboratoriesUNSPECIFIED
Issue or Number:6
Record Number:CaltechAUTHORS:20170222-145100100
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Official Citation:Palladium-Catalyzed Enantioselective Oxidation of Alcohols:  A Dramatic Rate Acceleration by Cs2CO3/t-BuOH Jeffrey T. Bagdanoff, Eric M. Ferreira, and Brian M. Stoltz Organic Letters 2003 5 (6), 835-837 DOI: 10.1021/ol027463p
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:74472
Deposited By: Ruth Sustaita
Deposited On:22 Feb 2017 23:03
Last Modified:11 Nov 2021 05:27

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