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Catalytic enantioselective stereoablative reactions: an unexploited approach to enantioselective catalysis

Mohr, Justin T. and Ebner, David C. and Stoltz, Brian M. (2007) Catalytic enantioselective stereoablative reactions: an unexploited approach to enantioselective catalysis. Organic and Biomolecular Chemistry, 5 (22). pp. 3571-3576. ISSN 1477-0520. PMCID PMC2963431. doi:10.1039/B711159M. https://resolver.caltech.edu/CaltechAUTHORS:20170223-071515692

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Abstract

Approaches to the preparation of enantioenriched materials via catalytic methods that destroy stereogenic elements of a molecule are discussed. Although these processes often decrease overall molecular complexity, there are several notable advantages including material recycling, enantiodivergence and convergence, and increased substrate scope. Examples are accompanied by discussion of the critical design elements required for the success of these methods.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1039/B711159MDOIArticle
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2963431PubMed CentralArticle
ORCID:
AuthorORCID
Mohr, Justin T.0000-0002-7005-3322
Stoltz, Brian M.0000-0001-9837-1528
Additional Information:© 2007 The Royal Society of Chemistry. Received 20 Jul 2007, Accepted 30 Aug 2007. First published online 01 Oct 2007. We thank NIH-NIGMS (R01 GM 080269-01), Eli Lilly (predoctoral fellowship to JTM), NDSEG (predoctoral fellowship to DCE), and NSF (predoctoral fellowship to DCE) for funding.
Funders:
Funding AgencyGrant Number
NIHR01GM080269-01
Eli LillyUNSPECIFIED
National Defense Science and Engineering Graduate (NDSEG) FellowshipUNSPECIFIED
NSF Predoctoral FellowshipUNSPECIFIED
Issue or Number:22
PubMed Central ID:PMC2963431
DOI:10.1039/B711159M
Record Number:CaltechAUTHORS:20170223-071515692
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20170223-071515692
Official Citation:Catalytic enantioselective stereoablative reactions: an unexploited approach to enantioselective catalysis Justin T. Mohr, David C. Ebner and Brian M. Stoltz Org. Biomol. Chem., 2007, 5, 3571-3576 DOI: 10.1039/B711159M
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:74485
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:23 Feb 2017 17:25
Last Modified:11 Nov 2021 05:27

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