Shi, Chunnian and Anson, Fred C. (2001) Selecting Experimental Conditions for Measurement of Rates of Electron-Transfer at Liquid/Liquid Interfaces by Thin-Layer Electrochemistry. Journal of Physical Chemistry B, 105 (5). pp. 1047-1049. ISSN 1520-6106. doi:10.1021/jp003741v. https://resolver.caltech.edu/CaltechAUTHORS:20170315-154112820
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Abstract
The use of thin layers of water-immiscible organic solvents on electrode surfaces to evaluate rates of electron-transfer across liquid/liquid interfaces requires that reactant concentrations in the two adjacent phases be selected to minimize the effects of mass transfer on the measured currents. A general inequality is derived which provides a guide to the selection of suitable concentrations of the coreactants. Experimental tests of the inequality demonstrated its utility and should allay recently expressed concerns about the reliability of the thin-layer methodology.
| Item Type: | Article | |||||||||
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| Additional Information: | © 2001 American Chemical Society. Received: October 12, 2000; In Final Form: November 28, 2000. Publication Date (Web): January 11, 2001. This work was supported by the National Science Foundation. Helpful comments from Prof. Carl Koval are acknowledged with appreciation. | |||||||||
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| Issue or Number: | 5 | |||||||||
| DOI: | 10.1021/jp003741v | |||||||||
| Record Number: | CaltechAUTHORS:20170315-154112820 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20170315-154112820 | |||||||||
| Official Citation: | Selecting Experimental Conditions for Measurement of Rates of Electron-Transfer at Liquid/Liquid Interfaces by Thin-Layer Electrochemistry Chunnian Shi and Fred C. Anson The Journal of Physical Chemistry B 2001 105 (5), 1047-1049 DOI: 10.1021/jp003741v | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 75160 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Tony Diaz | |||||||||
| Deposited On: | 16 Mar 2017 16:45 | |||||||||
| Last Modified: | 15 Nov 2021 16:31 |
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