Connick, William B. and Di Bilio, Angel J. and Schaeffer, William P. and Gray, Harry B. (1999) The red form of [Re(phen)(CO)_3(H_2O)]CF_3SO_3•H_2O. Acta Crystallographica Section C, 55 (6). pp. 913-916. ISSN 0108-2701. doi:10.1107/S0108270199001432. https://resolver.caltech.edu/CaltechAUTHORS:20170322-160013568
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Abstract
The coordination geometry of the cations in the red form of aquatricarbonyl(1,10-phenanthroline-N, N')rhenium(I) trifluoromethanesulfonate hydrate, [Re(C_(12)H_8N_2)(CO)_3- (H_2O)]CF_3SO_3•H_2O, is approximately octahedral, with a facial arrangement of the linearly coordinated carbonyl ligands. The phenanthroline (phen) ligands interleave to form a columnar r-stacked structure.
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| Additional Information: | © 1999 International Union of Crystallography. (Received 14 September 1998; accepted 26 January 1999) We thank L. M. Henling for expert assistance and helpful discussions. This work was supported by the National Science Foundation and the National Institutes of Health. | |||||||||
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| Issue or Number: | 6 | |||||||||
| DOI: | 10.1107/S0108270199001432 | |||||||||
| Record Number: | CaltechAUTHORS:20170322-160013568 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20170322-160013568 | |||||||||
| Official Citation: | Connick, W. B., Di Bilio, A. J., Schaeffer, W. P. & Gray, H. B. (1999). Acta Cryst. C55, 913-916. | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 75327 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | George Porter | |||||||||
| Deposited On: | 23 Mar 2017 20:17 | |||||||||
| Last Modified: | 15 Nov 2021 16:32 |
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