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Diastereoselective Povarov-Like Reaction Involving O-Pivaloylated D-Galactosylimine

Wang, Gang and Li, Boyu and Lou, Qinghua and Li, Zhongjun and Meng, Xiangbao (2013) Diastereoselective Povarov-Like Reaction Involving O-Pivaloylated D-Galactosylimine. Advanced Synthesis and Catalysis, 355 (2-3). pp. 303-307. ISSN 1615-4150. https://resolver.caltech.edu/CaltechAUTHORS:20170330-073929213

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Abstract

A diastereoselective Povarov-like reaction using O-pivaloylated β-D-galactosylamine as the chiral auxiliary is described. The three-component reaction of chiral aldimines, cyclic enol ethers and nucleophiles afforded the desired products in good yields and high content of the main isomer. This procedure provides an efficient method to obtain multifunctional molecules carrying three contiguous chiral centers in high stereoselectivity.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1002/adsc.201200761DOIArticle
http://onlinelibrary.wiley.com/doi/10.1002/adsc.201200761/abstractPublisherArticle
Additional Information:© 2013 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. Received: August 24, 2012; Published online: January 9, 2013. This work was supported by grants from the National Natural Science Foundation of China (NSFC) (No. 21072017, 20732001).
Funders:
Funding AgencyGrant Number
National Natural Science Foundation of China21072017
National Natural Science Foundation of China20732001
Issue or Number:2-3
Record Number:CaltechAUTHORS:20170330-073929213
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20170330-073929213
Official Citation:Wang, G., Li, B., Lou, Q., Li, Z. and Meng, X. (2013), Diastereoselective Povarov-Like Reaction Involving O-Pivaloylated D-Galactosylimine. Adv. Synth. Catal., 355: 303–307. doi:10.1002/adsc.201200761
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:75533
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:30 Mar 2017 15:05
Last Modified:03 Oct 2019 16:51

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