Hughes, E. W. and Wilmarth, W. K. and Calvin, M. (1946) The Oxygen-carrying Synthetic Chelate Compounds. V. Equilibrium with the Solid Compounds. Journal of the American Chemical Society, 68 (11). pp. 2273-2278. ISSN 0002-7863. doi:10.1021/ja01215a045. https://resolver.caltech.edu/CaltechAUTHORS:20170330-123356755
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Abstract
The preliminary study showed that the equilibrium oxygen pressure-was a function of the oxygen composition. The data indicate that the reaction is not simply the addition of oxygen to form the peroxide stoichiometrically with an accompanying phase change. However, the X-ray powder patterns of a chelate and its peroxide are distinctly different and, therefore, a phase change may be involved at some stage of the oxygenation. Powder patterns were then made of the chelate CoSaEn at various percentages of oxygenation. These data enable us to demonstrate a phase change and to fix the composition of the two phases existing during the process of phase change for this particular chelate.
| Item Type: | Article | |||||||||
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| Additional Information: | © 1946 American Chemical Society. Received April 30, 1946. | |||||||||
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| Issue or Number: | 11 | |||||||||
| DOI: | 10.1021/ja01215a045 | |||||||||
| Record Number: | CaltechAUTHORS:20170330-123356755 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20170330-123356755 | |||||||||
| Official Citation: | The Oxygen-carrying Synthetic Chelate Compounds. V. Equilibrium with the Solid Compounds E. W. Hughes, W. K. Wilmarth, and M. Calvin Journal of the American Chemical Society 1946 68 (11), 2273-2278 DOI: 10.1021/ja01215a045 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 75548 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | George Porter | |||||||||
| Deposited On: | 30 Mar 2017 21:37 | |||||||||
| Last Modified: | 15 Nov 2021 16:34 |
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