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The Oxygen-carrying Synthetic Chelate Compounds. V. Equilibrium with the Solid Compounds

Hughes, E. W. and Wilmarth, W. K. and Calvin, M. (1946) The Oxygen-carrying Synthetic Chelate Compounds. V. Equilibrium with the Solid Compounds. Journal of the American Chemical Society, 68 (11). pp. 2273-2278. ISSN 0002-7863. http://resolver.caltech.edu/CaltechAUTHORS:20170330-123356755

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Abstract

The preliminary study showed that the equilibrium oxygen pressure-was a function of the oxygen composition. The data indicate that the reaction is not simply the addition of oxygen to form the peroxide stoichiometrically with an accompanying phase change. However, the X-ray powder patterns of a chelate and its peroxide are distinctly different and, therefore, a phase change may be involved at some stage of the oxygenation. Powder patterns were then made of the chelate CoSaEn at various percentages of oxygenation. These data enable us to demonstrate a phase change and to fix the composition of the two phases existing during the process of phase change for this particular chelate.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://dx.doi.org/10.1021/ja01215a045DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja01215a045PublisherArticle
Additional Information:© 1946 American Chemical Society. Received April 30, 1946.
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Other Numbering System NameOther Numbering System ID
Gates and Crellin Laboratories of Chemistry1065
Record Number:CaltechAUTHORS:20170330-123356755
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20170330-123356755
Official Citation:The Oxygen-carrying Synthetic Chelate Compounds. V. Equilibrium with the Solid Compounds E. W. Hughes, W. K. Wilmarth, and M. Calvin Journal of the American Chemical Society 1946 68 (11), 2273-2278 DOI: 10.1021/ja01215a045
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:75548
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:30 Mar 2017 21:37
Last Modified:13 Feb 2019 18:03

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