Shin, Jun Ho and Churchill, David G. and Parkin, Gerard and Roggan, Stefan and Jankowski, Christel and Limberg, Christian and Tonks, Ian and Bercaw, John (2014) Bis(η⁵-Pentamethylcyclopentadienyl) Complexes of Molybdenum. In: Inorganic Syntheses. Vol.36. Wiley , Hoboken, NJ, pp. 58-62. ISBN 9781118744871. https://resolver.caltech.edu/CaltechAUTHORS:20170404-100242714
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Abstract
Molybdenocene and tungstenocene complexes have played a prominent role in the development of organometallic chemistry. This chapter describes the synthesis of (η⁵-C₅Me₅)₂MoCl₂ and (η⁵-C₅Me₅)₂MoH₂. (η⁵-C₅Me₅)₂MoCl₂ is obtained by a two-step sequence involving (i) the reaction of MoCl₅ with a mixture of KC₅Me₅ and NaBH₄ to give crude (η⁵-C₅Me₅)₂MoH₂, followed by (ii) addition of CHCl₃. (η⁵-C₅Me₅)₂MoCl₂ is a useful precursor for a variety of other permethylmolybdenocene derivatives, which include hydride, alkyl, carbonyl, and oxo complexes.
| Item Type: | Book Section | ||||||
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| Additional Information: | © 2014 John Wiley & Sons, Inc. Published Online: 11 APR 2014. The authors thank the U.S. Department of Energy, Office of Basic Energy Sciences (DE-FG02-93ER14339) for support of this research. | ||||||
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| Subject Keywords: | bis(pentamethylcyclopentadienyl) dichloromolybdenum(IV); bis(pentamethylcyclopentadienyl) dihydridomolybdenum(IV) | ||||||
| DOI: | 10.1002/9781118744994.ch12 | ||||||
| Record Number: | CaltechAUTHORS:20170404-100242714 | ||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20170404-100242714 | ||||||
| Official Citation: | Shin, J. H., Churchill, D. G., Parkin, G., Roggan, S., Jankowski, C., Limberg, C., Tonks, I. and Bercaw, J. (2014) Bis(η5-Pentamethylcyclopentadienyl) Complexes of Molybdenum, in Inorganic Syntheses: Volume 36 (eds G. S. Girolami and A. P. Sattelberger), John Wiley & Sons, Inc., Hoboken, NJ, USA. doi: 10.1002/9781118744994.ch12 | ||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
| ID Code: | 75681 | ||||||
| Collection: | CaltechAUTHORS | ||||||
| Deposited By: | Tony Diaz | ||||||
| Deposited On: | 04 Apr 2017 19:01 | ||||||
| Last Modified: | 03 Jun 2021 21:50 |
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