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Tandem Catalysis: Three Mechanistically Distinct Reactions from a Single Ruthenium Complex

Bielawski, Christopher W. and Louie, Janis and Grubbs, Robert H. (2000) Tandem Catalysis: Three Mechanistically Distinct Reactions from a Single Ruthenium Complex. Journal of the American Chemical Society, 122 (51). pp. 12872-12873. ISSN 0002-7863. http://resolver.caltech.edu/CaltechAUTHORS:20170404-100444243

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Abstract

Organometallic catalysts are traditionally designed and optimized to mediate a single reaction. As the number of applications that require combinatorial and other high-speed synthetic protocols increases, it will become desirable for catalysts to mediate multiple, mechanistically distinct transformations directly or upon simple modification. As an example of such a system, we demonstrate the ability of a single component precatalyst to mediate three different reactions to form well-defined block copolymers.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja001698jDOIArticle
http://pubs.acs.org/doi/full/10.1021/ja001698jPublisherArticle
http://pubs.acs.org/doi/suppl/10.1021/ja001698jRelated ItemSupporting Information
ORCID:
AuthorORCID
Bielawski, Christopher W.0000-0002-0520-1982
Grubbs, Robert H.0000-0002-0057-7817
Additional Information:© 2000 American Chemical Society. Received 17 May 2000. Published online 5 December 2000. Published in print 1 December 2000. C.B. is grateful to the National Science Foundation for a predoctoral fellowship. J.L. is grateful to the National Institute of Health for a postdoctoral fellowship.
Funders:
Funding AgencyGrant Number
NSF Predoctoral FellowshipUNSPECIFIED
NIH Postdoctoral FellowshipUNSPECIFIED
Record Number:CaltechAUTHORS:20170404-100444243
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20170404-100444243
Official Citation:Tandem Catalysis:  Three Mechanistically Distinct Reactions from a Single Ruthenium Complex Christopher W. Bielawski, Janis Louie, and Robert H. Grubbs Journal of the American Chemical Society 2000 122 (51), 12872-12873 DOI: 10.1021/ja001698j
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:75682
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:04 Apr 2017 18:59
Last Modified:04 Apr 2017 18:59

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