Grimm, Ronald L. and Beauchamp, J. L. (2003) Field-Induced Droplet Ionization Mass Spectrometry. Journal of Physical Chemistry B, 107 (51). pp. 14161-14163. ISSN 1520-6106. doi:10.1021/jp037099r. https://resolver.caltech.edu/CaltechAUTHORS:20170404-111317635
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Abstract
A neutral droplet elongates along the axis of a strong electric field, ejecting opposing jets of positively and negatively charged progeny droplets. Images of droplets from a vibrating orifice aerosol generator illustrate this phenomenon, and mass spectrometric sampling of the progeny droplets demonstrates that they are a viable source of desolvated gas-phase ions. Field-induced droplet ionization (FIDI) mass spectra are presented for several species, including tetraheptylammonium cation, deprotonated benzene tetracarboxylic acid anion, and multiply protonated cytochrome c.
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| Additional Information: | © 2003 American Chemical Society. Received: October 13, 2003; In Final Form: November 6, 2003. Publication Date (Web): November 27, 2003. The authors gratefully acknowledge Drs. Nathan Dalleska and Mona Shahgholi for the assistance with and use of their mass spectrometry facilities. The Beckman Institute at Caltech has provided facilities and financial support for these investigations. Studies of droplet evaporation and discharge processes associated with ESI have been supported by NSF Grant CHE-9727566. | |||||||||
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| Issue or Number: | 51 | |||||||||
| DOI: | 10.1021/jp037099r | |||||||||
| Record Number: | CaltechAUTHORS:20170404-111317635 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20170404-111317635 | |||||||||
| Official Citation: | Field-Induced Droplet Ionization Mass Spectrometry Ronald L. Grimm and and J. L. Beauchamp The Journal of Physical Chemistry B 2003 107 (51), 14161-14163 DOI: 10.1021/jp037099r | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 75695 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Tony Diaz | |||||||||
| Deposited On: | 04 Apr 2017 18:40 | |||||||||
| Last Modified: | 15 Nov 2021 16:35 |
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