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Field-Induced Droplet Ionization Mass Spectrometry

Grimm, Ronald L. and Beauchamp, J. L. (2003) Field-Induced Droplet Ionization Mass Spectrometry. Journal of Physical Chemistry B, 107 (51). pp. 14161-14163. ISSN 1520-6106. doi:10.1021/jp037099r. https://resolver.caltech.edu/CaltechAUTHORS:20170404-111317635

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Abstract

A neutral droplet elongates along the axis of a strong electric field, ejecting opposing jets of positively and negatively charged progeny droplets. Images of droplets from a vibrating orifice aerosol generator illustrate this phenomenon, and mass spectrometric sampling of the progeny droplets demonstrates that they are a viable source of desolvated gas-phase ions. Field-induced droplet ionization (FIDI) mass spectra are presented for several species, including tetraheptylammonium cation, deprotonated benzene tetracarboxylic acid anion, and multiply protonated cytochrome c.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/jp037099rDOIArticle
http://pubs.acs.org/doi/abs/10.1021/jp037099rPublisherArticle
ORCID:
AuthorORCID
Grimm, Ronald L.0000-0003-0407-937X
Beauchamp, J. L.0000-0001-8839-4822
Additional Information:© 2003 American Chemical Society. Received: October 13, 2003; In Final Form: November 6, 2003. Publication Date (Web): November 27, 2003. The authors gratefully acknowledge Drs. Nathan Dalleska and Mona Shahgholi for the assistance with and use of their mass spectrometry facilities. The Beckman Institute at Caltech has provided facilities and financial support for these investigations. Studies of droplet evaporation and discharge processes associated with ESI have been supported by NSF Grant CHE-9727566.
Funders:
Funding AgencyGrant Number
Caltech Beckman InstituteUNSPECIFIED
NSFCHE-9727566
Issue or Number:51
DOI:10.1021/jp037099r
Record Number:CaltechAUTHORS:20170404-111317635
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20170404-111317635
Official Citation:Field-Induced Droplet Ionization Mass Spectrometry Ronald L. Grimm and and J. L. Beauchamp The Journal of Physical Chemistry B 2003 107 (51), 14161-14163 DOI: 10.1021/jp037099r
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:75695
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:04 Apr 2017 18:40
Last Modified:15 Nov 2021 16:35

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