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Potentiometric Sensors Based on the Inductive Effect on the pK_a of Poly(aniline): A Nonenzymatic Glucose Sensor

Shoji, Eiichi and Freund, Michael S. (2001) Potentiometric Sensors Based on the Inductive Effect on the pK_a of Poly(aniline): A Nonenzymatic Glucose Sensor. Journal of the American Chemical Society, 123 (14). pp. 3383-3384. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20170406-071050116

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Abstract

The use of conjugated polymers for sensor applications continues to be the subject of intense research. In addition to their use as electronic conductors, they have been exploited as active sensing elements by coupling ligands to the backbone. In this approach, binding of an analyte results in physical distortions or changes in electron density, thereby altering conductivity. Poly(aniline), in particular, has received a great deal of attention due to its proton coupled redox chemistry and its resulting pH-dependent properties. For example, poly(aniline) has been used as a pH electrode and has been coupled to reactions that generate or consume protons to create sensors. Herein, we report a new strategy that exploits the inductive effect of reactive substituents on the pK_a of poly(aniline) to produce active sensing elements.


Item Type:Article
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URLURL TypeDescription
http://dx.doi.org/10.1021/ja005906jDOIArticle
http://pubs.acs.org/doi/full/10.1021/ja005906jPublisherArticle
http://pubs.acs.org/doi/suppl/10.1021/ja005906jPublisherSupporting Information
ORCID:
AuthorORCID
Freund, Michael S.0000-0003-1104-2292
Additional Information:© 2001 American Chemical Society. Received 20 December 2000. Published online 16 March 2001. Published in print 1 April 2001. We thank Professor Frances Arnold and Dr. Alan Michaels for helpful discussions. This work is dedicated to the memory of Dr. Alan Michaels.
Issue or Number:14
Record Number:CaltechAUTHORS:20170406-071050116
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20170406-071050116
Official Citation:Potentiometric Sensors Based on the Inductive Effect on the pKa of Poly(aniline):  A Nonenzymatic Glucose Sensor Eiichi Shoji and Michael S. Freund Journal of the American Chemical Society 2001 123 (14), 3383-3384 DOI: 10.1021/ja005906j
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:75770
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:06 Apr 2017 17:00
Last Modified:03 Oct 2019 16:54

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