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The Structure and Spin Coupling of Catalase Compound I: A Study of Noncovalent Effects

Green, Michael T. (2001) The Structure and Spin Coupling of Catalase Compound I: A Study of Noncovalent Effects. Journal of the American Chemical Society, 123 (37). pp. 9218-9219. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20170406-073511852

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Abstract

Catalase compound I contains an iron(lV)-oxo porphyrin- radical; in this species, an S = l iron-oxo unit and an S = 1/2 radical, located on the porphyrin ring, couple to give doublet and quartet states that are mixed by the zero-field splitting of the ferryl moiety. The result is a Kramer's doublet ground state with a distinctive EPR signature.


Item Type:Article
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URLURL TypeDescription
http://dx.doi.org/10.1021/ja010105hDOIArticle
http://pubs.acs.org/doi/full/10.1021/ja010105hPublisherArticle
Additional Information:© 2001 American Chemical Society. Received 11 January 2001. Published online 25 August 2001. Published in print 1 September 2001. I thank Harry Gray, the Burroughs-Wellcome Fund, and the National Institutes of Health for supporting this research.
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Burroughs Wellcome FundUNSPECIFIED
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Issue or Number:37
Record Number:CaltechAUTHORS:20170406-073511852
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20170406-073511852
Official Citation:The Structure and Spin Coupling of Catalase Compound I:  A Study of Noncovalent Effects Michael T. Green Journal of the American Chemical Society 2001 123 (37), 9218-9219 DOI: 10.1021/ja010105h
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:75773
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:06 Apr 2017 16:50
Last Modified:03 Oct 2019 16:54

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