Green, Michael T. (2001) The Structure and Spin Coupling of Catalase Compound I: A Study of Noncovalent Effects. Journal of the American Chemical Society, 123 (37). pp. 9218-9219. ISSN 0002-7863. doi:10.1021/ja010105h. https://resolver.caltech.edu/CaltechAUTHORS:20170406-073511852
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Abstract
Catalase compound I contains an iron(lV)-oxo porphyrin- radical; in this species, an S = l iron-oxo unit and an S = 1/2 radical, located on the porphyrin ring, couple to give doublet and quartet states that are mixed by the zero-field splitting of the ferryl moiety. The result is a Kramer's doublet ground state with a distinctive EPR signature.
| Item Type: | Article | |||||||||
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| Additional Information: | © 2001 American Chemical Society. Received 11 January 2001. Published online 25 August 2001. Published in print 1 September 2001. I thank Harry Gray, the Burroughs-Wellcome Fund, and the National Institutes of Health for supporting this research. | |||||||||
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| Issue or Number: | 37 | |||||||||
| DOI: | 10.1021/ja010105h | |||||||||
| Record Number: | CaltechAUTHORS:20170406-073511852 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20170406-073511852 | |||||||||
| Official Citation: | The Structure and Spin Coupling of Catalase Compound I: A Study of Noncovalent Effects Michael T. Green Journal of the American Chemical Society 2001 123 (37), 9218-9219 DOI: 10.1021/ja010105h | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 75773 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 06 Apr 2017 16:50 | |||||||||
| Last Modified: | 15 Nov 2021 16:36 |
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