CaltechAUTHORS
  A Caltech Library Service

Facile Functionalization of a Metal Carbon Bond by O-Atom Transfer

Conley, Brian L. and Ganesh, Somesh K. and Gonzales, Jason M. and Tenn, William J., III and Young, Kenneth J. H. and Oxgaard, Jonas and Goddard, William A., III and Periana, Roy A. (2006) Facile Functionalization of a Metal Carbon Bond by O-Atom Transfer. Journal of the American Chemical Society, 128 (28). pp. 9018-9019. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20170408-144146740

[img] PDF (Synthetic procedures and experimental details) - Supplemental Material
See Usage Policy.

154Kb

Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20170408-144146740

Abstract

The facile conversion of M−R to M−OR that could be useful for the functionalization of electron-rich metal alkyl intermediates is shown to proceed via a Baeyer−Villiger-type pathway involving a nonredox, electrophilic, O-atom insertion in reactions with non-peroxo O-donors.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja062417wDOIArticle
http://pubs.acs.org/doi/suppl/10.1021/ja062417wPublisherSupporting Information
ORCID:
AuthorORCID
Goddard, William A., III0000-0003-0097-5716
Periana, Roy A.0000-0001-7838-257X
Additional Information:© 2006 American Chemical Society. Received April 18, 2006. Publication Date (Web): June 27, 2006. The authors acknowledge the National Science Foundation (CHE-0328121) and Chevron Energy Technology Company for financial support of this research.
Funders:
Funding AgencyGrant Number
NSFCHE-0328121
Chevron Energy Technology CompanyUNSPECIFIED
Issue or Number:28
Record Number:CaltechAUTHORS:20170408-144146740
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20170408-144146740
Official Citation:Facile Functionalization of a Metal Carbon Bond by O-Atom Transfer Brian L. Conley, Somesh K. Ganesh, Jason M. Gonzales, William J. Tenn, III, Kenneth J. H. Young, Jonas Oxgaard, William A. Goddard, III, and Roy A. Periana Journal of the American Chemical Society 2006 128 (28), 9018-9019 DOI: 10.1021/ja062417w
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:75992
Collection:CaltechAUTHORS
Deposited By: 1Science Import
Deposited On:26 Apr 2017 23:28
Last Modified:03 Oct 2019 16:56

Repository Staff Only: item control page