Conley, Brian L. and Ganesh, Somesh K. and Gonzales, Jason M. and Tenn, William J., III and Young, Kenneth J. H. and Oxgaard, Jonas and Goddard, William A., III and Periana, Roy A. (2006) Facile Functionalization of a Metal Carbon Bond by O-Atom Transfer. Journal of the American Chemical Society, 128 (28). pp. 9018-9019. ISSN 0002-7863. doi:10.1021/ja062417w. https://resolver.caltech.edu/CaltechAUTHORS:20170408-144146740
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Abstract
The facile conversion of M−R to M−OR that could be useful for the functionalization of electron-rich metal alkyl intermediates is shown to proceed via a Baeyer−Villiger-type pathway involving a nonredox, electrophilic, O-atom insertion in reactions with non-peroxo O-donors.
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| Additional Information: | © 2006 American Chemical Society. Received April 18, 2006. Publication Date (Web): June 27, 2006. The authors acknowledge the National Science Foundation (CHE-0328121) and Chevron Energy Technology Company for financial support of this research. | |||||||||
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| Issue or Number: | 28 | |||||||||
| DOI: | 10.1021/ja062417w | |||||||||
| Record Number: | CaltechAUTHORS:20170408-144146740 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20170408-144146740 | |||||||||
| Official Citation: | Facile Functionalization of a Metal Carbon Bond by O-Atom Transfer Brian L. Conley, Somesh K. Ganesh, Jason M. Gonzales, William J. Tenn, III, Kenneth J. H. Young, Jonas Oxgaard, William A. Goddard, III, and Roy A. Periana Journal of the American Chemical Society 2006 128 (28), 9018-9019 DOI: 10.1021/ja062417w | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 75992 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | 1Science Import | |||||||||
| Deposited On: | 26 Apr 2017 23:28 | |||||||||
| Last Modified: | 15 Nov 2021 16:56 |
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