Shin, Seung Koo and Beauchamp, J. L. (1991) Infrared multiphoton dissociation spectrum of CF_3Mn(CO)_4I^-. Journal of Molecular Structure, 249 (1). pp. 1-9. ISSN 0022-2860. doi:10.1016/0022-2860(91)85050-D. https://resolver.caltech.edu/CaltechAUTHORS:20170408-172618697
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Abstract
An IR multiphoton dissociation spectrum of CF_3Mn(CO)_3I^− has been obtained using Fourier transform ion cyclotron resonance spectroscopy combined with a line-tunable CW CO_2 laser in the 925–1085 cm^(−1) wavelength range. The trifluoromethyl group in the anion shows two absorption maxima at 1055 and 975 cm^(−1), which correspond to a CF stretch of A_1- and E-type symmetry respectively. From comparisons of the ligand effect on the stretching force constant of CO in place of CF_3 in cis and trans isomeric CF_3Mn(CO)_4I^− ions, it is suggested that a cis isomer is responsible for the observed C-F stretching frequencies.
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| Alternate Title: | Infrared multiphoton dissociation spectrum of CF3Mn(CO)4I- | |||||||||
| Additional Information: | © 1991 Published by Elsevier. Received 7 September 1990. We acknowledge the support of the National Science Foundation (Grant No. CHE87-11567) and the donors of the Petroleum Research Fund, administered by the American Chemical Society. | |||||||||
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| Issue or Number: | 1 | |||||||||
| DOI: | 10.1016/0022-2860(91)85050-D | |||||||||
| Record Number: | CaltechAUTHORS:20170408-172618697 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20170408-172618697 | |||||||||
| Official Citation: | Seung Koo Shin, J.L. Beauchamp, Infrared multiphoton dissociation spectrum of CF3Mn (CO)4I−, Journal of Molecular Structure, Volume 249, Issue 1, 1991, Pages 1-9, ISSN 0022-2860, https://doi.org/10.1016/0022-2860(91)85050-D. (http://www.sciencedirect.com/science/article/pii/002228609185050D) | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 76345 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | 1Science Import | |||||||||
| Deposited On: | 29 Mar 2018 22:37 | |||||||||
| Last Modified: | 15 Nov 2021 16:59 |
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