Mead, Griffin J. and Alonso, Elena R. and Finneran, Ian A. and Carroll, P. Brandon and Blake, Geoffrey A. (2017) Identification of two conformationally trapped n-propanol-water dimers in a supersonic expansion. Journal of Molecular Spectroscopy, 335 . pp. 68-73. ISSN 0022-2852. https://resolver.caltech.edu/CaltechAUTHORS:20170410-073117094
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Abstract
Two conformers of the n-propanol-water dimer have been observed in a supersonic expansion using chirped-pulse Fourier-transform microwave (CPFTMW) spectroscopy. Structural assignments reveal the n-propanol sub-unit is conformationally trapped, with its methyl group in both Gauche and Trans orientations. Despite different carbon backbone conformations, both dimers display the same water-donor/alcohol-acceptor hydrogen bonding motif. This work builds upon other reported alcohol-water dimers and upon previous work detailing the trapping of small molecules into multiple structural minima in rare gas supersonic expansions.
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| Additional Information: | © 2017 Elsevier B.V. Received 12 January 2017, Accepted 15 March 2017, Available online 21 March 2017. The authors gratefully acknowledge assistance from Priya Chittur and the National Science Foundation Graduate Research Fellowship Program, the Ministerio de Ciencia e Innovación for an FPI grant (BES-2014-067776), and CSDM (CHE-1214123) Programs. | ||||||||||
| Group: | Astronomy Department | ||||||||||
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| Record Number: | CaltechAUTHORS:20170410-073117094 | ||||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20170410-073117094 | ||||||||||
| Official Citation: | Griffin J. Mead, Elena R. Alonso, Ian A. Finneran, P. Brandon Carroll, Geoffrey A. Blake, Identification of two conformationally trapped n-propanol-water dimers in a supersonic expansion, Journal of Molecular Spectroscopy, Volume 335, May 2017, Pages 68-73, ISSN 0022-2852, https://doi.org/10.1016/j.jms.2017.03.008. (http://www.sciencedirect.com/science/article/pii/S0022285217300097) | ||||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||
| ID Code: | 76463 | ||||||||||
| Collection: | CaltechAUTHORS | ||||||||||
| Deposited By: | Tony Diaz | ||||||||||
| Deposited On: | 10 Apr 2017 16:16 | ||||||||||
| Last Modified: | 10 Dec 2020 21:59 |
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