Mahammed, Atif and Gray, Harry B. and Meier-Callahan, Alexandre E. and Gross, Zeev (2003) Aerobic Oxidations Catalyzed by Chromium Corroles. Journal of the American Chemical Society, 125 (5). pp. 1162-1163. ISSN 0002-7863. doi:10.1021/ja028216j. https://resolver.caltech.edu/CaltechAUTHORS:20170417-064908538
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Abstract
Oxochromium(V) complexes of 5,10,15-tris(pentafluorophenyl)corrole and brominated derivatives oxygenate substrates (triphenylphosphine and norbornene) with concomitant production of chromium(III). Regeneration of Cr^VO by reaction of dioxygen with Cr^(III) completes an aerobic catalytic cycle, with very large solvent effects; in acetonitrile, rapid initial turnovers observed initially are shut down by formation of Cr^(IV)O, while in toluene, THF, and methanol, relatively slow reactions are further inhibited by product formation.
| Item Type: | Article | |||||||||
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| Additional Information: | © 2003 American Chemical Society. Received 20 August 2002. Published online 14 January 2003. Published in print 1 February 2003. This research was supported by the Israel Science Foundation under Grant 368/00 (Z.G.), the ACS Petroleum Research Fund (Z.G.), and NSF (H.B.G.). | |||||||||
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| Issue or Number: | 5 | |||||||||
| DOI: | 10.1021/ja028216j | |||||||||
| Record Number: | CaltechAUTHORS:20170417-064908538 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20170417-064908538 | |||||||||
| Official Citation: | Aerobic Oxidations Catalyzed by Chromium Corroles Atif Mahammed, Harry B. Gray, Alexandre E. Meier-Callahan, and Zeev Gross Journal of the American Chemical Society 2003 125 (5), 1162-1163 DOI: 10.1021/ja028216j | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 76580 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 17 Apr 2017 16:15 | |||||||||
| Last Modified: | 15 Nov 2021 17:01 |
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