Mahammed, Atif and Gray, Harry B. and Meier-Callahan, Alexandre E. and Gross, Zeev (2003) Aerobic Oxidations Catalyzed by Chromium Corroles. Journal of the American Chemical Society, 125 (5). pp. 1162-1163. ISSN 0002-7863. doi:10.1021/ja028216j. https://resolver.caltech.edu/CaltechAUTHORS:20170417-064908538
Full text is not posted in this repository. Consult Related URLs below.
Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20170417-064908538
Abstract
Oxochromium(V) complexes of 5,10,15-tris(pentafluorophenyl)corrole and brominated derivatives oxygenate substrates (triphenylphosphine and norbornene) with concomitant production of chromium(III). Regeneration of Cr^VO by reaction of dioxygen with Cr^(III) completes an aerobic catalytic cycle, with very large solvent effects; in acetonitrile, rapid initial turnovers observed initially are shut down by formation of Cr^(IV)O, while in toluene, THF, and methanol, relatively slow reactions are further inhibited by product formation.
Item Type: | Article | |||||||||
---|---|---|---|---|---|---|---|---|---|---|
Related URLs: |
| |||||||||
ORCID: |
| |||||||||
Additional Information: | © 2003 American Chemical Society. Received 20 August 2002. Published online 14 January 2003. Published in print 1 February 2003. This research was supported by the Israel Science Foundation under Grant 368/00 (Z.G.), the ACS Petroleum Research Fund (Z.G.), and NSF (H.B.G.). | |||||||||
Funders: |
| |||||||||
Issue or Number: | 5 | |||||||||
DOI: | 10.1021/ja028216j | |||||||||
Record Number: | CaltechAUTHORS:20170417-064908538 | |||||||||
Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20170417-064908538 | |||||||||
Official Citation: | Aerobic Oxidations Catalyzed by Chromium Corroles Atif Mahammed, Harry B. Gray, Alexandre E. Meier-Callahan, and Zeev Gross Journal of the American Chemical Society 2003 125 (5), 1162-1163 DOI: 10.1021/ja028216j | |||||||||
Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
ID Code: | 76580 | |||||||||
Collection: | CaltechAUTHORS | |||||||||
Deposited By: | Ruth Sustaita | |||||||||
Deposited On: | 17 Apr 2017 16:15 | |||||||||
Last Modified: | 15 Nov 2021 17:01 |
Repository Staff Only: item control page