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Highly Active Water-Soluble Olefin Metathesis Catalyst

Hong, Soon Hyeok and Grubbs, Robert H. (2006) Highly Active Water-Soluble Olefin Metathesis Catalyst. Journal of the American Chemical Society, 128 (11). pp. 3508-3509. ISSN 0002-7863. doi:10.1021/ja058451c. https://resolver.caltech.edu/CaltechAUTHORS:20170419-160942469

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Abstract

A novel water-soluble ruthenium olefin metathesis catalyst supported by a poly(ethylene glycol) conjugated saturated 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene ligand is reported. The catalyst displays improved activity in ring-opening metathesis polymerization, ring-closing metathesis, and cross-metathesis reactions in aqueous media.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja058451cDOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja058451cPublisherArticle
http://pubs.acs.org/doi/suppl/10.1021/ja058451cPublisherSupporting Information
ORCID:
AuthorORCID
Hong, Soon Hyeok0000-0003-0605-9735
Grubbs, Robert H.0000-0002-0057-7817
Additional Information:© 2006 American Chemical Society. Received December 13, 2005. Publication Date (Web): February 25, 2006. We would like to thank Jason P. Jordan for generous donation of substrate 12 and helpful discussions. The National Institutes of Health (5R01GM068647) is acknowledged for financial support.
Funders:
Funding AgencyGrant Number
NIH5R01GM068647
Issue or Number:11
DOI:10.1021/ja058451c
Record Number:CaltechAUTHORS:20170419-160942469
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20170419-160942469
Official Citation:Highly Active Water-Soluble Olefin Metathesis Catalyst Soon Hyeok Hong and Robert H. Grubbs Journal of the American Chemical Society 2006 128 (11), 3508-3509 DOI: 10.1021/ja058451c
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:76728
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:19 Apr 2017 23:20
Last Modified:15 Nov 2021 17:02

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