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Template-Directed One-Step Synthesis of Cyclic Trimers by ADMET

Hou, Hongyi and Leung, Ken C.-F. and Lanari, Daniela and Nelson, Alshakim and Stoddart, J. Fraser and Grubbs, Robert H. (2006) Template-Directed One-Step Synthesis of Cyclic Trimers by ADMET. Journal of the American Chemical Society, 128 (48). pp. 15358-15359. ISSN 0002-7863.

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A trifurcated template, containing three secondary dialkylammonium ion recognition sites for encirclement by a dibenzo [24]crown-8-containing acyclic diene, is used to promote acyclic diene metatheses (ADMET) catalyzed by ruthenium−alkylidene complexes, affording a cyclic trimer in 55% yield. Following this one-step, threefold ADMET reaction, the resulting cyclic trimer was isolated by preparative HPLC and characterized by NMR spectroscopy and mass spectrometry.

Item Type:Article
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URLURL TypeDescription Information
Stoddart, J. Fraser0000-0003-3161-3697
Grubbs, Robert H.0000-0002-0057-7817
Additional Information:© 2006 American Chemical Society. Received August 1, 2006. Publication Date (Web): November 9, 2006. We thank the office of Naval Research (ONR) for supporting this research through the Multidisciplinary University Research Initiative (MURI) program.
Funding AgencyGrant Number
Office of Naval Research (ONR)UNSPECIFIED
Issue or Number:48
Record Number:CaltechAUTHORS:20170420-105532746
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Official Citation:Template-Directed One-Step Synthesis of Cyclic Trimers by ADMET Hongyi Hou, Ken C.-F. Leung, Daniela Lanari, Alshakim Nelson, J. Fraser Stoddart, and Robert H. Grubbs Journal of the American Chemical Society 2006 128 (48), 15358-15359 DOI: 10.1021/ja065572j
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:76760
Deposited By: Tony Diaz
Deposited On:20 Apr 2017 18:38
Last Modified:03 Oct 2019 17:49

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