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Template-Directed One-Step Synthesis of Cyclic Trimers by ADMET

Hou, Hongyi and Leung, Ken C.-F. and Lanari, Daniela and Nelson, Alshakim and Stoddart, J. Fraser and Grubbs, Robert H. (2006) Template-Directed One-Step Synthesis of Cyclic Trimers by ADMET. Journal of the American Chemical Society, 128 (48). pp. 15358-15359. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20170420-105532746

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Abstract

A trifurcated template, containing three secondary dialkylammonium ion recognition sites for encirclement by a dibenzo [24]crown-8-containing acyclic diene, is used to promote acyclic diene metatheses (ADMET) catalyzed by ruthenium−alkylidene complexes, affording a cyclic trimer in 55% yield. Following this one-step, threefold ADMET reaction, the resulting cyclic trimer was isolated by preparative HPLC and characterized by NMR spectroscopy and mass spectrometry.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja065572jDOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja065572jPublisherArticle
http://pubs.acs.org/doi/suppl/10.1021/ja065572jPublisherSupporting Information
ORCID:
AuthorORCID
Stoddart, J. Fraser0000-0003-3161-3697
Grubbs, Robert H.0000-0002-0057-7817
Additional Information:© 2006 American Chemical Society. Received August 1, 2006. Publication Date (Web): November 9, 2006. We thank the office of Naval Research (ONR) for supporting this research through the Multidisciplinary University Research Initiative (MURI) program.
Funders:
Funding AgencyGrant Number
Office of Naval Research (ONR)UNSPECIFIED
Issue or Number:48
Record Number:CaltechAUTHORS:20170420-105532746
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20170420-105532746
Official Citation:Template-Directed One-Step Synthesis of Cyclic Trimers by ADMET Hongyi Hou, Ken C.-F. Leung, Daniela Lanari, Alshakim Nelson, J. Fraser Stoddart, and Robert H. Grubbs Journal of the American Chemical Society 2006 128 (48), 15358-15359 DOI: 10.1021/ja065572j
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:76760
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:20 Apr 2017 18:38
Last Modified:03 Oct 2019 17:49

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