Tenn, William J., III and Young, Kenneth J. H. and Bhalla, Gaurav and Oxgaard, Jonas and Goddard, William A., III and Periana, Roy A. (2005) CH Activation with an O-Donor Iridium−Methoxo Complex. Journal of the American Chemical Society, 127 (41). pp. 14172-14173. ISSN 0002-7863. doi:10.1021/ja051497l. https://resolver.caltech.edu/CaltechAUTHORS:20170421-080554867
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Abstract
A thermally and air stable O-donor, iridium−methoxo complex is reported that undergoes stoichiometric, intermolecular C−H activation of benzene with co-generation of methanol and the iridium−phenyl complex.
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| Additional Information: | © 2005 American Chemical Society. Received 9 March 2005. Published online 27 September 2005. Published in print 1 October 2005. The authors acknowledge the National Science Foundation (CHE-0328121) and Chevron Energy Technology Company for financial support for this research, M. Yousufuddin and Prof. Robert Bau for solving the crystal structure of 2-Py, and Steven K. Meier for synthetic assistance. | ||||||||||||
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| Issue or Number: | 41 | ||||||||||||
| DOI: | 10.1021/ja051497l | ||||||||||||
| Record Number: | CaltechAUTHORS:20170421-080554867 | ||||||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20170421-080554867 | ||||||||||||
| Official Citation: | CH Activation with an O-Donor Iridium−Methoxo Complex William J. Tenn, III, Kenneth J. H. Young, Gaurav Bhalla, Jonas Oxgaard, William A. Goddard, III, and Roy A. Periana Journal of the American Chemical Society 2005 127 (41), 14172-14173 DOI: 10.1021/ja051497l | ||||||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||||
| ID Code: | 76796 | ||||||||||||
| Collection: | CaltechAUTHORS | ||||||||||||
| Deposited By: | Ruth Sustaita | ||||||||||||
| Deposited On: | 21 Apr 2017 18:32 | ||||||||||||
| Last Modified: | 15 Nov 2021 17:02 |
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