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CH Activation with an O-Donor Iridium−Methoxo Complex

Tenn, William J., III and Young, Kenneth J. H. and Bhalla, Gaurav and Oxgaard, Jonas and Goddard, William A., III and Periana, Roy A. (2005) CH Activation with an O-Donor Iridium−Methoxo Complex. Journal of the American Chemical Society, 127 (41). pp. 14172-14173. ISSN 0002-7863. doi:10.1021/ja051497l. https://resolver.caltech.edu/CaltechAUTHORS:20170421-080554867

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Abstract

A thermally and air stable O-donor, iridium−methoxo complex is reported that undergoes stoichiometric, intermolecular C−H activation of benzene with co-generation of methanol and the iridium−phenyl complex.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja051497lDOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja051497lPublisherArticle
http://pubs.acs.org/doi/suppl/10.1021/ja051497lPublisherSupporting Information
ORCID:
AuthorORCID
Goddard, William A., III0000-0003-0097-5716
Periana, Roy A.0000-0001-7838-257X
Additional Information:© 2005 American Chemical Society. Received 9 March 2005. Published online 27 September 2005. Published in print 1 October 2005. The authors acknowledge the National Science Foundation (CHE-0328121) and Chevron Energy Technology Company for financial support for this research, M. Yousufuddin and Prof. Robert Bau for solving the crystal structure of 2-Py, and Steven K. Meier for synthetic assistance.
Funders:
Funding AgencyGrant Number
NSFCHE-0328121
Chevron Energy Technology CompanyUNSPECIFIED
Issue or Number:41
DOI:10.1021/ja051497l
Record Number:CaltechAUTHORS:20170421-080554867
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20170421-080554867
Official Citation:CH Activation with an O-Donor Iridium−Methoxo Complex William J. Tenn, III, Kenneth J. H. Young, Gaurav Bhalla, Jonas Oxgaard, William A. Goddard, III, and Roy A. Periana Journal of the American Chemical Society 2005 127 (41), 14172-14173 DOI: 10.1021/ja051497l
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:76796
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:21 Apr 2017 18:32
Last Modified:15 Nov 2021 17:02

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