Guidry, Erin N. and Li, Jean and Stoddart, J. Fraser and Grubbs, Robert H. (2007) Bifunctional [c2]Daisy-Chains and Their Incorporation into Mechanically Interlocked Polymers. Journal of the American Chemical Society, 129 (29). pp. 8944-8945. ISSN 0002-7863. doi:10.1021/ja0725100. https://resolver.caltech.edu/CaltechAUTHORS:20170421-090622527
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Abstract
A strategy for the formation of mechanically interlocked polymers is presented. Ring-closing olefin metathesis has been shown to provide a very high yielding route to [c2]daisy-chains suitably functionalized to allow their one-step conversion to bisolefins which can be used as monomers in ADMET polymerizations to afford mechanically interlocked polymers. Metathesis, in two different guises is making a hitherto unreachable goal in synthesis a reality.
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| Additional Information: | © 2007 American Chemical Society. Received April 10, 2007. Publication Date (Web): June 27, 2007. We would like to thank Drs. Stuart Cantrill, Al Nelson, and Anna Sanchez for useful discussions. The ruthenium metathesis catalyst was received as a generous gift from Materia. We thank Lawrence M. Henling and Dr. Michael W. Day for the X-ray crystallographic data. The work was supported by the Office of Naval Research through its MURI Program. | ||||||||||||
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| Issue or Number: | 29 | ||||||||||||
| DOI: | 10.1021/ja0725100 | ||||||||||||
| Record Number: | CaltechAUTHORS:20170421-090622527 | ||||||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20170421-090622527 | ||||||||||||
| Official Citation: | Bifunctional [c2]Daisy-Chains and Their Incorporation into Mechanically Interlocked Polymers Erin N. Guidry, Jean Li, J. Fraser Stoddart, and Robert H. Grubbs Journal of the American Chemical Society 2007 129 (29), 8944-8945 DOI: 10.1021/ja0725100 | ||||||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||||
| ID Code: | 76807 | ||||||||||||
| Collection: | CaltechAUTHORS | ||||||||||||
| Deposited By: | Tony Diaz | ||||||||||||
| Deposited On: | 21 Apr 2017 16:15 | ||||||||||||
| Last Modified: | 15 Nov 2021 17:02 |
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