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Bifunctional [c2]Daisy-Chains and Their Incorporation into Mechanically Interlocked Polymers

Guidry, Erin N. and Li, Jean and Stoddart, J. Fraser and Grubbs, Robert H. (2007) Bifunctional [c2]Daisy-Chains and Their Incorporation into Mechanically Interlocked Polymers. Journal of the American Chemical Society, 129 (29). pp. 8944-8945. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20170421-090622527

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Abstract

A strategy for the formation of mechanically interlocked polymers is presented. Ring-closing olefin metathesis has been shown to provide a very high yielding route to [c2]daisy-chains suitably functionalized to allow their one-step conversion to bisolefins which can be used as monomers in ADMET polymerizations to afford mechanically interlocked polymers. Metathesis, in two different guises is making a hitherto unreachable goal in synthesis a reality.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja0725100DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja0725100PublisherArticle
http://pubs.acs.org/doi/suppl/10.1021/ja0725100PublisherSupporting Information
ORCID:
AuthorORCID
Stoddart, J. Fraser0000-0003-3161-3697
Grubbs, Robert H.0000-0002-0057-7817
Additional Information:© 2007 American Chemical Society. Received April 10, 2007. Publication Date (Web): June 27, 2007. We would like to thank Drs. Stuart Cantrill, Al Nelson, and Anna Sanchez for useful discussions. The ruthenium metathesis catalyst was received as a generous gift from Materia. We thank Lawrence M. Henling and Dr. Michael W. Day for the X-ray crystallographic data. The work was supported by the Office of Naval Research through its MURI Program.
Funders:
Funding AgencyGrant Number
Office of Naval Research (ONR)UNSPECIFIED
Issue or Number:29
Record Number:CaltechAUTHORS:20170421-090622527
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20170421-090622527
Official Citation:Bifunctional [c2]Daisy-Chains and Their Incorporation into Mechanically Interlocked Polymers Erin N. Guidry, Jean Li, J. Fraser Stoddart, and Robert H. Grubbs Journal of the American Chemical Society 2007 129 (29), 8944-8945 DOI: 10.1021/ja0725100
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:76807
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:21 Apr 2017 16:15
Last Modified:03 Oct 2019 17:50

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