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Molecular Salts with Diquat-Based Electron Acceptors for Nonlinear Optics

Coe, Benjamin J. and Harris, James A. and Brunschwig, Bruce S. and Garín, Javier and Orduna, Jesús (2005) Molecular Salts with Diquat-Based Electron Acceptors for Nonlinear Optics. Journal of the American Chemical Society, 127 (10). pp. 3284-3285. ISSN 0002-7863. doi:10.1021/ja0431758. https://resolver.caltech.edu/CaltechAUTHORS:20170425-074745448

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Abstract

We have used several techniques, including Stark spectroscopy and MO calculations, to investigate the optical and electronic properties of two new dipolar chromophoric cations containing diquat-based electron acceptor groups. Both the Stark data and the calculated parameters show that the strong electron-accepting properties of a diquat unit lead to static first hyperpolarizabilities β_0 which are considerably larger than those of a related stilbazolium chromophore. In addition, one compound has a strongly 2D quadratic NLO response, providing a very rare example of a charged molecule displaying such behavior.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja0431758DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja0431758PublisherArticle
http://pubs.acs.org/doi/suppl/10.1021/ja0431758PublisherSupporting Information
ORCID:
AuthorORCID
Coe, Benjamin J.0000-0002-5998-3895
Brunschwig, Bruce S.0000-0002-6135-6727
Additional Information:© 2005 American Chemical Society. Received November 12, 2004. Publication Date (Web): February 19, 2005. We thank the EPSRC (GR/M93864) and MCyT-FEDER (BQU2002-00219) for support.
Funders:
Funding AgencyGrant Number
Engineering and Physical Sciences Research Council (EPSRC)GR/M93864
Ministerio de Ciencia y Tecnologia (MCyT)BQU2002-00219
Fondo Europeo de Desarrollo Regional (FEDER)UNSPECIFIED
Issue or Number:10
DOI:10.1021/ja0431758
Record Number:CaltechAUTHORS:20170425-074745448
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20170425-074745448
Official Citation:Molecular Salts with Diquat-Based Electron Acceptors for Nonlinear Optics Benjamin J. Coe, James A. Harris, Bruce S. Brunschwig, Javier Garín, and Jesús Orduna Journal of the American Chemical Society 2005 127 (10), 3284-3285 DOI: 10.1021/ja0431758
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:76897
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:25 Apr 2017 15:00
Last Modified:15 Nov 2021 17:03

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