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Antimony-121 Mössbauer Spectral Study of α-Zn_4Sb_3

Hermann, Raphaël P. and Grandjean, Fernande and Chen, Tsi-Chi and Brown, Dennis E. and Johnson, C. E. and Snyder, G. Jeffrey and Long, Gary J. (2007) Antimony-121 Mössbauer Spectral Study of α-Zn_4Sb_3. Inorganic Chemistry, 46 (3). pp. 767-770. ISSN 0020-1669. doi:10.1021/ic061533x. https://resolver.caltech.edu/CaltechAUTHORS:20170425-081144066

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Abstract

The Mössbauer spectra of α-Zn_4Sb_3, a compound that is best formulated as α-Zn_(13)Sb_(10) or (Zn^(2+))_(13)(Sb^(3-))_6(Sb_2^(4-))2, have been measured between 5 and 120 K. The resulting six spectra have been simultaneously fit with two components in the ratio of 3:2 corresponding to the Sb^(3-) and Sb^(2-) ions identified in this valence semiconductor. The fits yield temperature independent isomer shifts of −8.17(2) and −9.73(2) mm/s and quadrupole interactions of −4.9(2) and 0 mm/s for the Sb^(3-) and Sb^(2-) ions, respectively; the corresponding Mössbauer temperatures are 197(5) and 207(5) K, temperatures that are lower than the Debye temperature of β-Zn_4Sb_3. The isomer shifts correspond to electronic configurations between 5s^25p^6 and 5s^(1.75)5p^(4.01) for the Sb^(3-) ions and between 5s^25p^5 and 5s^(1.80)5p^(3.38) for the Sb^(2-) ions, configurations that are in good agreement with the expected configurations for this valence semiconductor and with the results of band structure calculations.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ic061533xDOIArticle
http://pubs.acs.org/doi/abs/10.1021/ic061533xPublisherArticle
ORCID:
AuthorORCID
Hermann, Raphaël P.0000-0002-6138-5624
Snyder, G. Jeffrey0000-0003-1414-8682
Additional Information:© 2007 American Chemical Society. Received 14 August 2006. Published online 5 January 2007. Published in print 1 February 2007.
Issue or Number:3
DOI:10.1021/ic061533x
Record Number:CaltechAUTHORS:20170425-081144066
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20170425-081144066
Official Citation:Antimony-121 Mössbauer Spectral Study of α-Zn4Sb3 Raphaël P. Hermann, Fernande Grandjean, Tsi-Chi Chen, Dennis E. Brown, C. E. Johnson, G. Jeffrey Snyder, and Gary J. Long Inorganic Chemistry 2007 46 (3), 767-770 DOI: 10.1021/ic061533x
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:76900
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:25 Apr 2017 19:28
Last Modified:15 Nov 2021 17:03

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