Hong, Soon Hyeok and Day, Michael W. and Grubbs, Robert H. (2004) Decomposition of a Key Intermediate in Ruthenium-Catalyzed Olefin Metathesis Reactions. Journal of the American Chemical Society, 126 (24). pp. 7414-7415. ISSN 0002-7863. doi:10.1021/ja0488380. https://resolver.caltech.edu/CaltechAUTHORS:20170425-082022653
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Abstract
Dinuclear ruthenium complex, with a bridging carbide and a hydride ligand, and methyltricyclohexylphosphonium chloride result from thermal decomposition of olefin metathesis catalyst, (ImesH_2)(PCy)_3)(Cl)_2Ru CH_2. Involvement of dissociated phosphine in the decomposition is proposed. The dinuclear complex has catalytic olefin isomerization activity, which can be responsible for competing isomerization processes in certain olefin metathesis reactions.
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| Additional Information: | © 2004 American Chemical Society. Received March 1, 2004. Publication Date (Web): May 28, 2004. We thank Lawrence M. Henling for X-ray crystallography. Prof. J. A. Love, Dr. C. W. Lee, Dr. A. Chlenov, and Dr. P. L. Diaconescu are also acknowledged for helpful discussions and critical reading of the manuscript. This research was supported by the National Science Foundation. | ||||||||||||
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| Issue or Number: | 24 | ||||||||||||
| DOI: | 10.1021/ja0488380 | ||||||||||||
| Record Number: | CaltechAUTHORS:20170425-082022653 | ||||||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20170425-082022653 | ||||||||||||
| Official Citation: | Decomposition of a Key Intermediate in Ruthenium-Catalyzed Olefin Metathesis Reactions Soon Hyeok Hong, Michael W. Day, and Robert H. Grubbs Journal of the American Chemical Society 2004 126 (24), 7414-7415 DOI: 10.1021/ja0488380 | ||||||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||||
| ID Code: | 76901 | ||||||||||||
| Collection: | CaltechAUTHORS | ||||||||||||
| Deposited By: | Tony Diaz | ||||||||||||
| Deposited On: | 25 Apr 2017 15:56 | ||||||||||||
| Last Modified: | 15 Nov 2021 17:03 |
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