CaltechAUTHORS
  A Caltech Library Service

Decomposition of a Key Intermediate in Ruthenium-Catalyzed Olefin Metathesis Reactions

Hong, Soon Hyeok and Day, Michael W. and Grubbs, Robert H. (2004) Decomposition of a Key Intermediate in Ruthenium-Catalyzed Olefin Metathesis Reactions. Journal of the American Chemical Society, 126 (24). pp. 7414-7415. ISSN 0002-7863. http://resolver.caltech.edu/CaltechAUTHORS:20170425-082022653

[img] PDF (Crystallographic data of 8, experimental details, and characterization data) - Supplemental Material
See Usage Policy.

288Kb
[img] Crystallographic Info File (CIF) - Supplemental Material
See Usage Policy.

27Kb

Use this Persistent URL to link to this item: http://resolver.caltech.edu/CaltechAUTHORS:20170425-082022653

Abstract

Dinuclear ruthenium complex, with a bridging carbide and a hydride ligand, and methyltricyclohexylphosphonium chloride result from thermal decomposition of olefin metathesis catalyst, (ImesH_2)(PCy)_3)(Cl)_2Ru CH_2. Involvement of dissociated phosphine in the decomposition is proposed. The dinuclear complex has catalytic olefin isomerization activity, which can be responsible for competing isomerization processes in certain olefin metathesis reactions.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja0488380DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja0488380PublisherArticle
http://pubs.acs.org/doi/suppl/10.1021/ja0488380PublisherSupporting Information
ORCID:
AuthorORCID
Hong, Soon Hyeok0000-0003-0605-9735
Grubbs, Robert H.0000-0002-0057-7817
Additional Information:© 2004 American Chemical Society. Received March 1, 2004. Publication Date (Web): May 28, 2004. We thank Lawrence M. Henling for X-ray crystallography. Prof. J. A. Love, Dr. C. W. Lee, Dr. A. Chlenov, and Dr. P. L. Diaconescu are also acknowledged for helpful discussions and critical reading of the manuscript. This research was supported by the National Science Foundation.
Funders:
Funding AgencyGrant Number
NSFUNSPECIFIED
Record Number:CaltechAUTHORS:20170425-082022653
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20170425-082022653
Official Citation:Decomposition of a Key Intermediate in Ruthenium-Catalyzed Olefin Metathesis Reactions Soon Hyeok Hong, Michael W. Day, and Robert H. Grubbs Journal of the American Chemical Society 2004 126 (24), 7414-7415 DOI: 10.1021/ja0488380
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:76901
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:25 Apr 2017 15:56
Last Modified:25 Apr 2017 15:56

Repository Staff Only: item control page