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Hyperbranched Macromolecules via Olefin Metathesis

Gorodetskaya, Irina A. and Choi, Tae-Lim and Grubbs, Robert H. (2007) Hyperbranched Macromolecules via Olefin Metathesis. Journal of the American Chemical Society, 129 (42). pp. 12672-12673. ISSN 0002-7863. doi:10.1021/ja0759040. https://resolver.caltech.edu/CaltechAUTHORS:20170425-101026161

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Abstract

A facile route to hyperbranched polymers via acyclic diene metathesis is reported. Any molecule functionalized with two or more acrylate groups and one terminal olefin can serve as an AB_n monomer when exposed to an imidazolinylidene-based ruthenium olefin metathesis catalyst, due to the cross metathesis selectivity of this catalyst. For the polymers obtained by this method, both ^1H NMR spectroscopy and triple detector size exclusion chromatography conclusively indicate a branched architecture.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja0759040DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja0759040PublisherArticle
http://pubs.acs.org/doi/suppl/10.1021/ja0759040PublisherSupporting Information
ORCID:
AuthorORCID
Choi, Tae-Lim0000-0001-9521-6450
Grubbs, Robert H.0000-0002-0057-7817
Additional Information:© 2007 American Chemical Society. Received August 6, 2007. Publication Date (Web): September 29, 2007. We gratefully acknowledge Materia, Inc. for the generous gift of catalyst 1. We also thank Wyatt Technology Corp., especially Dr. Michelle Chen and Dr. Jeffrey Ahlgren for help with the SEC analysis and instrumentation. This research was supported by the office of Naval Research (ONR) through the Multidisciplinary University Research Initiative (MURI) program and NSF.
Funders:
Funding AgencyGrant Number
Office of Naval Research (ONR)UNSPECIFIED
NSFUNSPECIFIED
Issue or Number:42
DOI:10.1021/ja0759040
Record Number:CaltechAUTHORS:20170425-101026161
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20170425-101026161
Official Citation:Hyperbranched Macromolecules via Olefin Metathesis Irina A. Gorodetskaya, Tae-Lim Choi, and Robert H. Grubbs Journal of the American Chemical Society 2007 129 (42), 12672-12673 DOI: 10.1021/ja0759040
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:76908
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:25 Apr 2017 19:16
Last Modified:15 Nov 2021 17:03

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