Agapie, Theodor (2017) Mechanistic insight into the cleavage and coupling of CO with molybdenum complexes: Toward upgrading oxygenated C1 precursors. In: 253rd American Chemical Society National Meeting & Exposition, April 2-6, 2017, San Francisco, CA. https://resolver.caltech.edu/CaltechAUTHORS:20170503-143024986
Full text is not posted in this repository. Consult Related URLs below.
Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20170503-143024986
Abstract
CO reductive coupling chem. has been demonstrated with Mo complexes supported by multidentate terphenyl diphosphine ligands. Low temp. synthetic, kinetics, and isotopic labeling studies have been performed to gain mechanistic insight into CO activation chem. Four- and two-electron coupling chem. to C_2 species as well as further CO enchainment to C_3 species were obsd. Deoxygenation chem. occurs via a terminal Mocarbide species which acts as a precursor to C-C coupling chem. with CO. The redox non-innocent and labile pendant arene donor is instrumental for the obsd. reactivity.
| Item Type: | Conference or Workshop Item (Paper) | ||||||
|---|---|---|---|---|---|---|---|
| Related URLs: |
| ||||||
| ORCID: |
| ||||||
| Additional Information: | © 2017 American Chemical Society. | ||||||
| Record Number: | CaltechAUTHORS:20170503-143024986 | ||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20170503-143024986 | ||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
| ID Code: | 77162 | ||||||
| Collection: | CaltechAUTHORS | ||||||
| Deposited By: | Tony Diaz | ||||||
| Deposited On: | 04 May 2017 01:36 | ||||||
| Last Modified: | 03 Oct 2019 17:54 |
Repository Staff Only: item control page
