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A CaMn_4O_2 model of the biological oxygen evolving complex: synthesis via cluster expansion on a low symmetry ligand

Lee, Heui Beom and Tsui, Emily Y. and Agapie, Theodor (2017) A CaMn_4O_2 model of the biological oxygen evolving complex: synthesis via cluster expansion on a low symmetry ligand. Chemical Communications, 53 (51). pp. 6832-6835. ISSN 1359-7345. PMCID PMC5508601. https://resolver.caltech.edu/CaltechAUTHORS:20170509-083819492

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Abstract

Using a new multinucleating ligand featuring two dipyridyl alkoxide moieties and a carboxylate moiety, low symmetry tetranuclear complexes 1-M (M = Mn, Fe, and Co) have been synthesized. Complex 1-Mn was used as a precursor for the synthesis of a pentanuclear CaMn_4O_2 cluster (3) with the same metal stoichiometry as the biological OEC.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1039/c7cc02313hDOIArticle
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5508601PubMed CentralArticle
ORCID:
AuthorORCID
Lee, Heui Beom0000-0002-9550-2649
Tsui, Emily Y.0000-0001-6419-3954
Agapie, Theodor0000-0002-9692-7614
Additional Information:© 2017 The Royal Society of Chemistry. The article was received on 27 Mar 2017, accepted on 25 Apr 2017 and first published on 25 Apr 2017. This work was supported by the NIH (R01-GM102687B), Caltech, a Sandia Campus Executive Fellowship (E. Y. T.) and a Dreyfus fellowship (T. A.).
Funders:
Funding AgencyGrant Number
NIHR01-GM102687B
CaltechUNSPECIFIED
Sandia National LaboratoriesUNSPECIFIED
Camille and Henry Dreyfus FoundationUNSPECIFIED
Issue or Number:51
PubMed Central ID:PMC5508601
Record Number:CaltechAUTHORS:20170509-083819492
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20170509-083819492
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:77290
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:12 May 2017 22:37
Last Modified:04 Mar 2020 22:06

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