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Rate Acceleration in Olefin Metathesis through a Fluorine−Ruthenium Interaction

Ritter, Tobias and Day, Michael W. and Grubbs, Robert H. (2006) Rate Acceleration in Olefin Metathesis through a Fluorine−Ruthenium Interaction. Journal of the American Chemical Society, 128 (36). pp. 11768-11769. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20170509-160741000

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Abstract

The synthesis, structure, and performance of new ruthenium-based olefin metathesis catalysts, featuring fluorinated NHC ligands are presented. The introduction of halogen atoms into the N-heterocyclic carbene ligand profoundly alters the catalytic activity and can afford a more efficient catalyst. Structural investigations suggest that a fluorine−ruthenium interaction is responsible for this increased activity.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja064091xDOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja064091xPublisherArticle
http://pubs.acs.org/doi/suppl/10.1021/ja064091xPublisherSupporting Information
ORCID:
AuthorORCID
Grubbs, Robert H.0000-0002-0057-7817
Additional Information:© 2006 American Chemical Society. Received June 21, 2006. Publication Date (Web): August 22, 2006. Larry M. Henling is acknowledged for X-ray crystallographic analysis. We thank Donde Anderson and Prof. Daniel J. O'Leary for helpful discussions and NMR studies. T.R. thanks the German Academic Exchange Service (DAAD) for a postdoctoral fellowship.
Funders:
Funding AgencyGrant Number
Deutscher Akademischer Austauschdienst (DAAD)UNSPECIFIED
Issue or Number:36
Record Number:CaltechAUTHORS:20170509-160741000
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20170509-160741000
Official Citation:Rate Acceleration in Olefin Metathesis through a Fluorine−Ruthenium Interaction Tobias Ritter, Michael W. Day, and Robert H. Grubbs Journal of the American Chemical Society 2006 128 (36), 11768-11769 DOI: 10.1021/ja064091x
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:77317
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:16 May 2017 21:58
Last Modified:03 Oct 2019 17:56

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