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Iridium Corroles

Palmer, Joshua H. and Day, Michael W. and Wilson, Aaron D. and Henling, Lawrence M. and Gross, Zeev and Gray, Harry B. (2008) Iridium Corroles. Journal of the American Chemical Society, 130 (25). pp. 7786-7787. ISSN 0002-7863. http://resolver.caltech.edu/CaltechAUTHORS:20170512-130427477

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Abstract

This work reports the synthesis and full characterization of 5,10,15-tris-pentafluorophenylcorrolato-iridium(III) bis-trimethylamine 1 and its octabromo derivative 2. The corrole is planar in both cases (the mean deviation from the plane is as low as 0.0371 Å for 1 and 0.0325 Å for 2), the UV−vis spectra display a split Soret band with a shoulder attributable to an MLCT transition, and cyclic voltammetry reveals that the iridium(II) oxidation state cannot be accessed, while the oxidation to formal iridium(IV) complexes is achieved at much lower potentials than in other coordination environments.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja801049tDOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja801049tPublisherArticle
http://pubs.acs.org/doi/suppl/10.1021/ja801049tPublisherSupporting Information
Additional Information:© 2008 American Chemical Society. Received February 11, 2008. Publication Date (Web): May 31, 2008. This work was supported by the US-Israel BSF (Z.G. and H.B.G.), BP, NSF, CCSER (Gordon and Betty Moore Foundation), and the Arnold and Mabel Beckman Foundation (H.B.G.).
Funders:
Funding AgencyGrant Number
Binational Science Foundation (USA-Israel)UNSPECIFIED
BPUNSPECIFIED
NSFUNSPECIFIED
Caltech Center for Sustainable Energy ResearchUNSPECIFIED
Gordon and Betty Moore FoundationUNSPECIFIED
Arnold and Mabel Beckman FoundationUNSPECIFIED
Record Number:CaltechAUTHORS:20170512-130427477
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20170512-130427477
Official Citation:Iridium Corroles Joshua H. Palmer, Michael W. Day, Aaron D. Wilson, Lawrence M. Henling, Zeev Gross, and Harry B. Gray Journal of the American Chemical Society 2008 130 (25), 7786-7787 DOI: 10.1021/ja801049t
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:77417
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:12 May 2017 23:29
Last Modified:12 May 2017 23:29

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