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An Electrochemical Color-Switchable RGB Dye: Tristable [2]Catenane

Deng, Wei-Qiao and Flood, Amar H. and Stoddart, J. Fraser and Goddard, William A. (2005) An Electrochemical Color-Switchable RGB Dye: Tristable [2]Catenane. Journal of the American Chemical Society, 127 (46). pp. 15994-15995. ISSN 0002-7863. doi:10.1021/ja0431298. https://resolver.caltech.edu/CaltechAUTHORS:20170516-072218828

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Abstract

We propose a design for an electrochemically driven RGB dye based on a tristable [2]catenane, in which the color of the molecule can be switched between Red, Green, and Blue by merely changing voltage. Based on DFT calculations, we conclude that the tristable [2]catenane should consist of a CBPQT^(4+) ring interlocked with a polyether macrocyle containing DNP (red), TTF (green), and FBZD (blue) units as the tunable RGB color-generating donors. Thus, at controllable voltages 0, V_1, and V_2, the [2]catenane is expected to display green, blue, and red colors, respectively. The advent of these RGB tristable molecules may have potential applications in low cost paperlike electronic displays.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja0431298DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja0431298PublisherArticle
http://pubs.acs.org/doi/suppl/10.1021/ja0431298PublisherSupporting Information
ORCID:
AuthorORCID
Stoddart, J. Fraser0000-0003-3161-3697
Goddard, William A.0000-0003-0097-5716
Additional Information:© 2005 American Chemical Society. Received 15 November 2004. Published online 1 November 2005. Published in print 23 November 2005. We thank Paul Bonvallet (UCLA) for helpful discussions. This research was supported by MSC internal grants (Caltech) and MARCO-FENA (Caltech, UCLA). In addition the MSC is supported by MURI-ARO, MURI-ONR, DOE (ASC, FETL), NSF (CHE), NIH, Aventis Pharma, ChevronTexaco, Nissan Corp., Berlix Biopharma, and Beckman Institute.
Funders:
Funding AgencyGrant Number
Microelectronics Advanced Research Corporation (MARCO)UNSPECIFIED
Center on Functional Engineered NanoArchitectonics (FENA)UNSPECIFIED
Army Research Office (ARO)UNSPECIFIED
Office of Naval Research (ONR)UNSPECIFIED
Department of Energy (DOE)UNSPECIFIED
NSFUNSPECIFIED
NIHUNSPECIFIED
Aventis PharmaUNSPECIFIED
ChevronTexacoUNSPECIFIED
Nissan Corp.UNSPECIFIED
Berlix BiopharmaUNSPECIFIED
Caltech Beckman InstituteUNSPECIFIED
Issue or Number:46
DOI:10.1021/ja0431298
Record Number:CaltechAUTHORS:20170516-072218828
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20170516-072218828
Official Citation:An Electrochemical Color-Switchable RGB Dye:  Tristable [2]Catenane Wei-Qiao Deng, Amar H. Flood, J. Fraser Stoddart, and William A. Goddard III Journal of the American Chemical Society 2005 127 (46), 15994-15995 DOI: 10.1021/ja0431298
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:77483
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:16 May 2017 16:37
Last Modified:15 Nov 2021 17:31

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