Shi, Chunnian and Anson, Fred C. (2001) Rates of Electron-Transfer Across Liquid/Liquid Interfaces. Effects of Changes in Driving Force and Reaction Reversibility. Journal of Physical Chemistry B, 105 (37). pp. 8963-8969. ISSN 1520-6106. doi:10.1021/jp010465r. https://resolver.caltech.edu/CaltechAUTHORS:20170516-073937933
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Abstract
Rates of electron-transfer between redox reactants located on opposite sides of the interface between thin layers of organic solvents on graphite electrode and aqueous solutions were measured by means of steady-state electrochemistry. Changes in the overall driving forces for irreversible reactions produced changes in rate that fit no simple behavioral pattern. For reversible reactions, a regular increase in rate with driving force was obtained. Evidence for a significant effect of diffuse-layer potentials on reaction rates was not found.
| Item Type: | Article | |||||||||
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| Additional Information: | © 2001 American Chemical Society. Received: February 7, 2001; In Final Form: May 13, 2001. Publication Date (Web): June 23, 2001. This work was supported by the National Science Foundation. We appreciated receiving a pre-print of reference 26 prior to its publication. | |||||||||
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| Issue or Number: | 37 | |||||||||
| DOI: | 10.1021/jp010465r | |||||||||
| Record Number: | CaltechAUTHORS:20170516-073937933 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20170516-073937933 | |||||||||
| Official Citation: | Rates of Electron-Transfer Across Liquid/Liquid Interfaces. Effects of Changes in Driving Force and Reaction Reversibility Chunnian Shi and Fred C. Anson The Journal of Physical Chemistry B 2001 105 (37), 8963-8969 DOI: 10.1021/jp010465r | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 77484 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Tony Diaz | |||||||||
| Deposited On: | 16 May 2017 16:34 | |||||||||
| Last Modified: | 15 Nov 2021 17:31 |
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