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Rates of Electron-Transfer Across Liquid/Liquid Interfaces. Effects of Changes in Driving Force and Reaction Reversibility

Shi, Chunnian and Anson, Fred C. (2001) Rates of Electron-Transfer Across Liquid/Liquid Interfaces. Effects of Changes in Driving Force and Reaction Reversibility. Journal of Physical Chemistry B, 105 (37). pp. 8963-8969. ISSN 1520-6106. https://resolver.caltech.edu/CaltechAUTHORS:20170516-073937933

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Abstract

Rates of electron-transfer between redox reactants located on opposite sides of the interface between thin layers of organic solvents on graphite electrode and aqueous solutions were measured by means of steady-state electrochemistry. Changes in the overall driving forces for irreversible reactions produced changes in rate that fit no simple behavioral pattern. For reversible reactions, a regular increase in rate with driving force was obtained. Evidence for a significant effect of diffuse-layer potentials on reaction rates was not found.


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http://dx.doi.org/10.1021/jp010465rDOIArticle
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Additional Information:© 2001 American Chemical Society. Received: February 7, 2001; In Final Form: May 13, 2001. Publication Date (Web): June 23, 2001. This work was supported by the National Science Foundation. We appreciated receiving a pre-print of reference 26 prior to its publication.
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Issue or Number:37
Record Number:CaltechAUTHORS:20170516-073937933
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20170516-073937933
Official Citation:Rates of Electron-Transfer Across Liquid/Liquid Interfaces. Effects of Changes in Driving Force and Reaction Reversibility Chunnian Shi and Fred C. Anson The Journal of Physical Chemistry B 2001 105 (37), 8963-8969 DOI: 10.1021/jp010465r
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:77484
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:16 May 2017 16:34
Last Modified:03 Oct 2019 17:58

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