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Design of photovoltaics for modules with 50% efficiency

Warmann, Emily C. and Flowers, Cristofer and Lloyd, John and Eisler, Carissa N. and Escarra, Matthew D. and Atwater, Harry A. (2017) Design of photovoltaics for modules with 50% efficiency. Energy Science and Engineering, 5 (2). pp. 69-80. ISSN 2050-0505. doi:10.1002/ese3.155.

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We describe a spectrum splitting solar module design approach using ensembles of 2–20 subcells with bandgaps optimized for the AM1.5D spectrum. Device physics calculations and experimental data determine radiative efficiency parameters for III-V compound semiconductor subcells and enable modification of conventional detailed balance calculations to predict module efficiency while retaining computational speed for a wide search of the design space. Accounting for nonideal absorption and recombination rates due to realistic material imperfections allows us to identify the minimum subcell quantity, quality, electrical connection configuration, and concentration required for 50% module efficiency with realistic optical losses and modeled contact resistance losses. We predict a module efficiency of 50% or greater will be possible with 7–10 electrically independent subcells in a spectral splitting optic at 300–500 suns concentration, assuming a 90% optical efficiency and 98% electrical efficiency, provided the subcells can achieve an average external radiative efficiency of 3–5% and a short circuit current that is at least 90% of the ideal. In examining spectrum splitting solar cells with both series-connected and electrically independent subcells, we identify a new design trade-off independent of the challenges of fabricating optimal bandgap combinations. Series-connected ensembles, having a single set of electrical contacts, are less sensitive to lumped series resistance losses than ensembles where each subcells are contacted independently. By contrast, ensembles with electrically independent subcells can achieve lower radiative losses when the subcells are designed for good optical confinement. Distributing electrically independent subcells in a concentrating receiver module allows flexibility in subcell selection and fabrication, and can achieve ultra-high efficiency with conventional III-V cell technology.

Item Type:Article
Related URLs:
URLURL TypeDescription
Warmann, Emily C.0000-0002-2810-4608
Flowers, Cristofer0000-0001-7864-3629
Eisler, Carissa N.0000-0002-5755-5280
Escarra, Matthew D.0000-0002-0232-942X
Atwater, Harry A.0000-0001-9435-0201
Additional Information:© 2017 The Authors. Energy Science & Engineering published by the Society of Chemical Industry and John Wiley & Sons Ltd. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. Issue online: 24 April 2017. Version of record online: 10 April 2017. Manuscript Accepted: 1 March 2017. Manuscript Revised: 21 February 2017. Manuscript Received: 23 November 2016. Dow Chemical Company (Grant/Award Number: ‘Full spectrum photovoltaics’); National Science Foundation (Grant/Award Number: ‘EEC-1041895’); Advanced Research Projects Agency – Energy (Grant/Award Number: ‘DE-SC0001293’).
Funding AgencyGrant Number
Dow Chemical CompanyUNSPECIFIED
Department of Energy (DOE)DE-SC0001293
Subject Keywords:Efficiency, photovoltaic design, photovoltaic modules, spectrum splitting
Issue or Number:2
Record Number:CaltechAUTHORS:20170518-085341562
Persistent URL:
Official Citation:Warmann, E. C., Flowers, C., Lloyd, J., Eisler, C. N., Escarra, M. D. and Atwater, H. A. (2017), Design of photovoltaics for modules with 50% efficiency. Energy Sci Eng, 5: 69–80. doi:10.1002/ese3.155
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:77555
Deposited By: Ruth Sustaita
Deposited On:18 May 2017 16:11
Last Modified:15 Nov 2021 17:32

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