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High-Valent Manganese Corroles and the First Perhalogenated Metallocorrole Catalyst

Golubkov, Galina and Bendix, Jesper and Gray, Harry B. and Mahammed, Atif and Goldberg, Israel and Di Bilio, Angel J. and Gross, Zeev (2001) High-Valent Manganese Corroles and the First Perhalogenated Metallocorrole Catalyst. Angewandte Chemie International Edition in English, 40 (11). pp. 2132-2134. ISSN 0570-0833. doi:10.1002/1521-3773(20010601)40:11<2132::AID-ANIE2132>3.0.CO;2-5.

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On pyrrole! The pyrrole-based corrole ligands can offer an alternative to porphyrin systems. The manganese corroles 1–4 are readily synthesized, undergo metal- not ligand-based redox chemistry, and 4 in particular shows impressive catalytic activity in the oxygenation of styrene with iodosylbenzene.

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URLURL TypeDescription<2132::AID-ANIE2132>3.0.CO;2-5DOIArticle;2-5/abstractPublisherArticle
Gray, Harry B.0000-0002-7937-7876
Additional Information:© 2001 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany. Issue online: 28 May 2001. Version of Record online: 28 May 2001. Manuscript Received: 17 Jan 2001. This research (No. 368/00) was supported by the Israel Science Foundation (Z.G.), the US National Science Foundation (H.B.G.), and the Fund for the Promotion of Research at the Technion (Z.G.).
Funding AgencyGrant Number
Israel Science Foundation368/00
Issue or Number:11
Record Number:CaltechAUTHORS:20170602-151432131
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Official Citation:Golubkov, G., Bendix, J., Gray, H. B., Mahammed, A., Goldberg, I., DiBilio, A. J. and Gross, Z. (2001), High-Valent Manganese Corroles and the First Perhalogenated Metallocorrole Catalyst . Angewandte Chemie International Edition, 40: 2132–2134.
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:77928
Deposited By: Ruth Sustaita
Deposited On:03 Jun 2017 01:32
Last Modified:15 Nov 2021 17:35

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