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Direct Functionalization of C−H Bonds by Iron, Nickel, and Cobalt Catalysis

Pototschnig, Gerit and Maulide, Nuno and Schnürch, Michael (2017) Direct Functionalization of C−H Bonds by Iron, Nickel, and Cobalt Catalysis. Chemistry: a European Journal, 23 (39). pp. 9206-9232. ISSN 0947-6539. doi:10.1002/chem.201605657.

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Non-precious-metal-catalyzed reactions are of increasing importance in chemistry due to the outstanding ecological and economic properties of these metals. In the subfield of metal-catalyzed direct C−H functionalization reactions, recent years have shown an increasing number of publications dedicated to this topic. Nickel, cobalt, and last but not least iron, have started to enter a field which was long dominated by precious metals such as palladium, rhodium, ruthenium, and iridium. The present review article summarizes the development of iron-, nickel-, and cobalt-catalyzed C−H functionalization reactions until the end of 2016, and discusses the scope and limitations of these transformations.

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Additional Information:© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. Manuscript received: December 3, 2016; Revised manuscript received: February 8, 2017; Accepted manuscript online: April 21, 2017; Version of record online: June 7, 2017.
Subject Keywords:base metal catalysis; C−H activation; cobalt; iron; nickel
Issue or Number:39
Record Number:CaltechAUTHORS:20170607-123436929
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Official Citation:G. Pototschnig, N. Maulide, M. Schnürch, Chem. Eur. J. 2017, 23, 9206
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:78004
Deposited By: Tony Diaz
Deposited On:07 Jun 2017 21:38
Last Modified:15 Nov 2021 17:35

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