CaltechAUTHORS
  A Caltech Library Service

Synthesis of Symmetrical Trisubstituted Olefins by Cross Metathesis

Chatterjee, Arnab K. and Sanders, Daniel P. and Grubbs, Robert H. (2002) Synthesis of Symmetrical Trisubstituted Olefins by Cross Metathesis. Organic Letters, 4 (11). pp. 1939-1942. ISSN 1523-7060. doi:10.1021/ol0259793. https://resolver.caltech.edu/CaltechAUTHORS:20170607-142937932

Full text is not posted in this repository. Consult Related URLs below.

Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20170607-142937932

Abstract

Trisubstituted alkenes have been prepared via intermolecular olefin cross-metathesis (CM) between α-olefins and symmetrically 1,1-disubstituted olefins using an imidazolylidene ruthenium benzylidene complex. Of particular interest is the synthesis of isoprenoid/prenyl groups by a simple solvent-free CM reaction with isobutylene. In addition, prenyl groups can also be installed by a cross-metathesis of 2-methyl-2-butene with a variety of α-olefins at room temperature with low catalyst loadings.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ol0259793DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ol0259793PublisherArticle
ORCID:
AuthorORCID
Grubbs, Robert H.0000-0002-0057-7817
Additional Information:© 2002 American Chemical Society. Received April 5, 2002. Publication Date (Web): May 4, 2002. The authors would like to thank Dr. Eric F. Connor, Dr. F. Dean Toste, Dr. Jennifer A. Love, John P. Morgan, and Tina M. Trnka for useful discussions and encouragement. Support has been generously provided by the National Institutes of Health.
Funders:
Funding AgencyGrant Number
NIHUNSPECIFIED
Issue or Number:11
DOI:10.1021/ol0259793
Record Number:CaltechAUTHORS:20170607-142937932
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20170607-142937932
Official Citation:Synthesis of Symmetrical Trisubstituted Olefins by Cross Metathesis Arnab K. Chatterjee, Daniel P. Sanders, and Robert H. Grubbs Organic Letters 2002 4 (11), 1939-1942 DOI: 10.1021/ol0259793
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:78013
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:07 Jun 2017 21:43
Last Modified:15 Nov 2021 17:35

Repository Staff Only: item control page