Chatterjee, Arnab K. and Sanders, Daniel P. and Grubbs, Robert H. (2002) Synthesis of Symmetrical Trisubstituted Olefins by Cross Metathesis. Organic Letters, 4 (11). pp. 1939-1942. ISSN 1523-7060. doi:10.1021/ol0259793. https://resolver.caltech.edu/CaltechAUTHORS:20170607-142937932
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Abstract
Trisubstituted alkenes have been prepared via intermolecular olefin cross-metathesis (CM) between α-olefins and symmetrically 1,1-disubstituted olefins using an imidazolylidene ruthenium benzylidene complex. Of particular interest is the synthesis of isoprenoid/prenyl groups by a simple solvent-free CM reaction with isobutylene. In addition, prenyl groups can also be installed by a cross-metathesis of 2-methyl-2-butene with a variety of α-olefins at room temperature with low catalyst loadings.
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| Additional Information: | © 2002 American Chemical Society. Received April 5, 2002. Publication Date (Web): May 4, 2002. The authors would like to thank Dr. Eric F. Connor, Dr. F. Dean Toste, Dr. Jennifer A. Love, John P. Morgan, and Tina M. Trnka for useful discussions and encouragement. Support has been generously provided by the National Institutes of Health. | |||||||||
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| Issue or Number: | 11 | |||||||||
| DOI: | 10.1021/ol0259793 | |||||||||
| Record Number: | CaltechAUTHORS:20170607-142937932 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20170607-142937932 | |||||||||
| Official Citation: | Synthesis of Symmetrical Trisubstituted Olefins by Cross Metathesis Arnab K. Chatterjee, Daniel P. Sanders, and Robert H. Grubbs Organic Letters 2002 4 (11), 1939-1942 DOI: 10.1021/ol0259793 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 78013 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Tony Diaz | |||||||||
| Deposited On: | 07 Jun 2017 21:43 | |||||||||
| Last Modified: | 15 Nov 2021 17:35 |
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