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A Fischer Indolization Strategy toward the Total Synthesis of (–)-Goniomitine

Pritchett, Beau P. and Kikuchi, Jun and Numajiri, Yoshitaka and Stoltz, Brian M. (2017) A Fischer Indolization Strategy toward the Total Synthesis of (–)-Goniomitine. Heterocycles, 95 (2). pp. 1245-1253. ISSN 0385-5414. PMCID PMC5502790. doi:10.3987/COM-16-S(S)80.

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A Fischer indolization strategy toward the core of (–)-goniomitine is reported. Initial investigations into the Pd-catalyzed asymmetric allylic alkylation of dihydropyrido[1,2-a]indolone (DHPI) substrates are also discussed.

Item Type:Article
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URLURL TypeDescription DOIArticle CentralArticle
Pritchett, Beau P.0000-0001-9922-9160
Stoltz, Brian M.0000-0001-9837-1528
Additional Information:© 2017 The Japan Institute of Heterocyclic Chemistry. Published online: 15th February, 2017. The authors wish to thank NIH-NIGMS (R01GM080269), Amgen, the Gordon and Betty Moore Foundation, and Caltech for financial support. B.P.P. thanks the NSF for a predoctoral fellowship (Grant DGE-1144469). Y. N. thanks Toray Industries Inc. for a postdoctoral fellowship. The authors thank Dr. Scott Virgil (Caltech) and the Caltech Center for Catalysis and Chemical Synthesis, for instrumentation assistance. Katerina Korch is acknowledged for experimental assistance.
Funding AgencyGrant Number
Gordon and Betty Moore FoundationUNSPECIFIED
NSF Graduate Research FellowshipDGE-1144469
Toray Industries Inc.UNSPECIFIED
Issue or Number:2
PubMed Central ID:PMC5502790
Record Number:CaltechAUTHORS:20170706-132827697
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Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:78814
Deposited By: Tony Diaz
Deposited On:06 Jul 2017 21:17
Last Modified:05 Apr 2022 17:39

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