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Saturation of Hydrogen Sorption in Zn Benzenedicarboxylate and Zn Naphthalenedicarboxylate

Dailly, Anne and Vajo, John J. and Ahn, Channing C. (2006) Saturation of Hydrogen Sorption in Zn Benzenedicarboxylate and Zn Naphthalenedicarboxylate. Journal of Physical Chemistry B, 110 (3). pp. 1099-1101. ISSN 1520-6106. https://resolver.caltech.edu/CaltechAUTHORS:20170711-114327364

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Abstract

We report excess hydrogen saturation values from high-pressure isotherms of metal organic framework structures taken at 77 K. Zn benzendicarboxylate (IRMOF-1) and Zn naphthalendicarboxylate (IRMOF-8) linker structures show identical saturation values of 137 hydrogen molecules on a per unit cell basis, despite the higher sorption potential of IRMOF-8 of 6.1 kJ/mol over that of IRMOF-1 of 4.1kJ/mol. Charge transfer between linker and vertex, as well as surface area, appear to dominate the sorption behavior, over that of linker length in these two systems.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/jp0563538DOIArticle
http://pubs.acs.org/doi/abs/10.1021/jp0563538PublisherArticle
ORCID:
AuthorORCID
Vajo, John J.0000-0002-6271-4899
Additional Information:© 2006 American Chemical Society. Received 3 November 2005. Published online 4 January 2006. Published in print 1 January 2006. This work was supported by the DoE through DE-FC36-05GO15079, and by the Chemical and Environmental Sciences Laboratory of General Motors Research and Development Center. We thank N. Gallego and F. Baker for the activated carbon sample. We also thank R. Yazami, R. C. Bowman, Jr., B. Fultz, and A. Gross for useful discussions and R. Doty for initial help with the thermodynamic analysis.
Funders:
Funding AgencyGrant Number
Department of Energy (DOE)DE-FC36-05GO15079
General Motors Research and Development CenterUNSPECIFIED
Issue or Number:3
Record Number:CaltechAUTHORS:20170711-114327364
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20170711-114327364
Official Citation:Saturation of Hydrogen Sorption in Zn Benzenedicarboxylate and Zn Naphthalenedicarboxylate Anne Dailly, John J. Vajo, and Channing C. Ahn The Journal of Physical Chemistry B 2006 110 (3), 1099-1101 DOI: 10.1021/jp0563538
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:78947
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:11 Jul 2017 21:08
Last Modified:09 Mar 2020 13:19

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