Hejl, Andrew and Scherman, Oren A. and Grubbs, Robert H. (2005) Ring-Opening Metathesis Polymerization of Functionalized Low-Strain Monomers with Ruthenium-Based Catalysts. Macromolecules, 38 (17). pp. 7214-7218. ISSN 0024-9297. doi:10.1021/ma0501287. https://resolver.caltech.edu/CaltechAUTHORS:20170724-112902291
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Abstract
A detailed study of the ring-opening metathesis polymerization of low-strain monomers with ruthenium catalysts is reported. The effects of monomer concentration and catalyst dependence are described for unsubstituted cycloolefins. The ROMP of low-strain olefins with polar substituents is also examined with ruthenium olefin metathesis catalysts, and a predictive model for ROMP feasibility is proposed.
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| Additional Information: | © 2005 American Chemical Society. Received 20 January 2005. Published online 29 July 2005. Published in print 1 August 2005. The authors thank Daniel P. Sanders and Prof. Dennis A. Dougherty for helpful discussions. This work was supported by the NSF. | |||||||||
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| Issue or Number: | 17 | |||||||||
| DOI: | 10.1021/ma0501287 | |||||||||
| Record Number: | CaltechAUTHORS:20170724-112902291 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20170724-112902291 | |||||||||
| Official Citation: | Ring-Opening Metathesis Polymerization of Functionalized Low-Strain Monomers with Ruthenium-Based Catalysts Andrew Hejl, Oren A. Scherman, and Robert H. Grubbs Macromolecules 2005 38 (17), 7214-7218 DOI: 10.1021/ma0501287 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 79303 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 24 Jul 2017 20:44 | |||||||||
| Last Modified: | 15 Nov 2021 17:47 |
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