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Poly(aniline boronic acid): A New Precursor to Substituted Poly(aniline)s

Shoji, Eiichi and Freund, Michael S. (2001) Poly(aniline boronic acid): A New Precursor to Substituted Poly(aniline)s. Langmuir, 17 (23). pp. 7183-7185. ISSN 0743-7463. doi:10.1021/la0114272.

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A novel strategy for preparing a wide range of substituted poly(aniline)s from a single precursor is described. This approach relies on a boron activation/electrophilic displacement reaction resulting in ipso-substitution. Specifically, we demonstrate this strategy to prepare a few of the many possible structures that can be generated from poly(aniline boronic acid), including poly(hydroxyaniline) and halogenated poly(aniline)s. The ability to tune the properties of poly(aniline) through the generation of these new structures will be useful in diverse fields where poly(aniline) is used ranging from polymer-based electronics to sensors.

Item Type:Article
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URLURL TypeDescription Information
Freund, Michael S.0000-0003-1104-2292
Additional Information:© 2001 American Chemical Society. Received 11 September 2001. Published online 10 October 2001. Published in print 1 November 2001. This work was supported by the Arnold and Mabel Beckman Foundation.
Funding AgencyGrant Number
Arnold and Mabel Beckman FoundationUNSPECIFIED
Issue or Number:23
Record Number:CaltechAUTHORS:20170725-083146448
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Official Citation:Poly(aniline boronic acid):  A New Precursor to Substituted Poly(aniline)s Eiichi Shoji and Michael S. Freund Langmuir 2001 17 (23), 7183-7185 DOI: 10.1021/la0114272
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:79321
Deposited By: Ruth Sustaita
Deposited On:25 Jul 2017 16:23
Last Modified:15 Nov 2021 17:47

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