Shoji, Eiichi and Freund, Michael S. (2001) Poly(aniline boronic acid): A New Precursor to Substituted Poly(aniline)s. Langmuir, 17 (23). pp. 7183-7185. ISSN 0743-7463. https://resolver.caltech.edu/CaltechAUTHORS:20170725-083146448
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Abstract
A novel strategy for preparing a wide range of substituted poly(aniline)s from a single precursor is described. This approach relies on a boron activation/electrophilic displacement reaction resulting in ipso-substitution. Specifically, we demonstrate this strategy to prepare a few of the many possible structures that can be generated from poly(aniline boronic acid), including poly(hydroxyaniline) and halogenated poly(aniline)s. The ability to tune the properties of poly(aniline) through the generation of these new structures will be useful in diverse fields where poly(aniline) is used ranging from polymer-based electronics to sensors.
Item Type: | Article | ||||||||||||
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Additional Information: | © 2001 American Chemical Society. Received 11 September 2001. Published online 10 October 2001. Published in print 1 November 2001. This work was supported by the Arnold and Mabel Beckman Foundation. | ||||||||||||
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Issue or Number: | 23 | ||||||||||||
Record Number: | CaltechAUTHORS:20170725-083146448 | ||||||||||||
Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20170725-083146448 | ||||||||||||
Official Citation: | Poly(aniline boronic acid): A New Precursor to Substituted Poly(aniline)s Eiichi Shoji and Michael S. Freund Langmuir 2001 17 (23), 7183-7185 DOI: 10.1021/la0114272 | ||||||||||||
Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||||
ID Code: | 79321 | ||||||||||||
Collection: | CaltechAUTHORS | ||||||||||||
Deposited By: | Ruth Sustaita | ||||||||||||
Deposited On: | 25 Jul 2017 16:23 | ||||||||||||
Last Modified: | 03 Oct 2019 18:18 |
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