Bhalla, Gaurav and Oxgaard, Jonas and Goddard, William A., III and Periana, Roy A. (2005) Hydrovinylation of Olefins Catalyzed by an Iridium Complex via CH Activation. Organometallics, 24 (23). pp. 5499-5502. ISSN 0276-7333. doi:10.1021/om050614i. https://resolver.caltech.edu/CaltechAUTHORS:20170725-150701014
![]() |
Crystallographic Info File (CIF)
- Supplemental Material
See Usage Policy. 11kB |
![]() |
PDF
- Supplemental Material
See Usage Policy. 93kB |
Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20170725-150701014
Abstract
Olefin dimerizations are typically proposed to proceed via a Cossee−Arlman type migratory mechanism involving relatively electron-rich metal hydrides. We provide experimental evidence and theoretical calculations that show, in contrast, relatively electron-poor O-donor Ir complexes can catalyze the dimerization of olefins via a mechanism that involves olefin CH bond activation and insertion into a metal−vinyl intermediate.
Item Type: | Article | ||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Related URLs: |
| ||||||||||||
ORCID: |
| ||||||||||||
Additional Information: | © 2005 American Chemical Society. Received 22 July 2005. Published online 14 October 2005. Published in print 1 November 2005. The authors acknowledge Chevron Energy Technology Company, the National Science Foundation (CHE-0328121), the Loker Hydrocarbon Institute, and the University of Southern California for financial support. We acknowledge Mr. M. Yousufuddin and Prof. Robert Bau for solving the crystal structure of Vinyl−Ir−Py. The preparative procedure, spectroscopic data, elemental analysis data, and crystallographic data sets for theVinyl-Ir-Py complex as well as experimental details of the reactions discussed are available free of charge via the Internet at http//pubs.acs.org. | ||||||||||||
Funders: |
| ||||||||||||
Issue or Number: | 23 | ||||||||||||
DOI: | 10.1021/om050614i | ||||||||||||
Record Number: | CaltechAUTHORS:20170725-150701014 | ||||||||||||
Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20170725-150701014 | ||||||||||||
Official Citation: | Hydrovinylation of Olefins Catalyzed by an Iridium Complex via CH Activation Gaurav Bhalla, Jonas Oxgaard, William A. Goddard, III, and Roy A. Periana Organometallics 2005 24 (23), 5499-5502 DOI: 10.1021/om050614i | ||||||||||||
Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||||
ID Code: | 79352 | ||||||||||||
Collection: | CaltechAUTHORS | ||||||||||||
Deposited By: | Ruth Sustaita | ||||||||||||
Deposited On: | 25 Jul 2017 22:45 | ||||||||||||
Last Modified: | 15 Nov 2021 17:47 |
Repository Staff Only: item control page