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Chemoselective Construction of Substituted Conjugated Dienes Using an Olefin Cross-Metathesis Protocol

Funk, Timothy W. and Efskind, Jon and Grubbs, Robert H. (2005) Chemoselective Construction of Substituted Conjugated Dienes Using an Olefin Cross-Metathesis Protocol. Organic Letters, 7 (2). pp. 187-190. ISSN 1523-7060. doi:10.1021/ol047929z. https://resolver.caltech.edu/CaltechAUTHORS:20170726-074601198

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Abstract

Various substituted conjugated dienes have been made by olefin cross-metathesis. Using either electronic or steric “protection,” one of the olefins of the conjugated diene was deactivated relative to the other for cross-metathesis. The reactions proceed with very high chemoselectivity and, when steric deactivation is used, very high diastereoselectivity.


Item Type:Article
Related URLs:
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http://dx.doi.org/10.1021/ol047929zDOIArticle
http://pubs.acs.org/doi/suppl/10.1021/ol047929zPublisherSupporting Information
ORCID:
AuthorORCID
Funk, Timothy W.0000-0002-8828-1446
Grubbs, Robert H.0000-0002-0057-7817
Additional Information:© 2005 American Chemical Society. Received 7 October 2004. Published online 22 December 2004. Published in print 1 January 2005. This work was supported by a research grant from the National Institutes of Health.
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Issue or Number:2
DOI:10.1021/ol047929z
Record Number:CaltechAUTHORS:20170726-074601198
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20170726-074601198
Official Citation:Chemoselective Construction of Substituted Conjugated Dienes Using an Olefin Cross-Metathesis Protocol Timothy W. Funk, Jon Efskind, and Robert H. Grubbs Organic Letters 2005 7 (2), 187-190 DOI: 10.1021/ol047929z
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:79384
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:26 Jul 2017 22:25
Last Modified:15 Nov 2021 17:47

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