Funk, Timothy W. and Efskind, Jon and Grubbs, Robert H. (2005) Chemoselective Construction of Substituted Conjugated Dienes Using an Olefin Cross-Metathesis Protocol. Organic Letters, 7 (2). pp. 187-190. ISSN 1523-7060. doi:10.1021/ol047929z. https://resolver.caltech.edu/CaltechAUTHORS:20170726-074601198
![[img]](https://authors.library.caltech.edu/style/images/fileicons/application_pdf.png) |
PDF
- Supplemental Material
See Usage Policy. 138kB |
|
PDF
- Supplemental Material
See Usage Policy. 264kB |
Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20170726-074601198
Abstract
Various substituted conjugated dienes have been made by olefin cross-metathesis. Using either electronic or steric “protection,” one of the olefins of the conjugated diene was deactivated relative to the other for cross-metathesis. The reactions proceed with very high chemoselectivity and, when steric deactivation is used, very high diastereoselectivity.
| Item Type: | Article | |||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Related URLs: |
| |||||||||
| ORCID: |
| |||||||||
| Additional Information: | © 2005 American Chemical Society. Received 7 October 2004. Published online 22 December 2004. Published in print 1 January 2005. This work was supported by a research grant from the National Institutes of Health. | |||||||||
| Funders: |
| |||||||||
| Issue or Number: | 2 | |||||||||
| DOI: | 10.1021/ol047929z | |||||||||
| Record Number: | CaltechAUTHORS:20170726-074601198 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20170726-074601198 | |||||||||
| Official Citation: | Chemoselective Construction of Substituted Conjugated Dienes Using an Olefin Cross-Metathesis Protocol Timothy W. Funk, Jon Efskind, and Robert H. Grubbs Organic Letters 2005 7 (2), 187-190 DOI: 10.1021/ol047929z | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 79384 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 26 Jul 2017 22:25 | |||||||||
| Last Modified: | 15 Nov 2021 17:47 |
Repository Staff Only: item control page
