Waltman, Andrew W. and Younkin, Todd R. and Grubbs, Robert H. (2004) Insights into the Deactivation of Neutral Nickel Ethylene Polymerization Catalysts in the Presence of Functionalized Olefins. Organometallics, 23 (22). pp. 5121-5123. ISSN 0276-7333. doi:10.1021/om049360b. https://resolver.caltech.edu/CaltechAUTHORS:20170726-091441043
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Abstract
A study on the products of reaction between a neutral nickel(II) olefin polymerization catalyst and methyl acrylate is presented. A deactivation mechanism involving hydrogen transfer from substrate to catalyst is suggested.
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Additional Information: | © 2004 American Chemical Society. Received 18 August 2004. Published online 29 September 2004. Published in print 1 October 2004. We thank the Rohm and Haas Corp. for funding, Dr. Mona Shahgholi for mass spectral analysis, and Jonathan Owen and Raissa Trend for helpful discussions. | ||||||||||||
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Issue or Number: | 22 | ||||||||||||
DOI: | 10.1021/om049360b | ||||||||||||
Record Number: | CaltechAUTHORS:20170726-091441043 | ||||||||||||
Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20170726-091441043 | ||||||||||||
Official Citation: | Insights into the Deactivation of Neutral Nickel Ethylene Polymerization Catalysts in the Presence of Functionalized Olefins Andrew W. Waltman, Todd R. Younkin, and Robert H. Grubbs Organometallics 2004 23 (22), 5121-5123 DOI: 10.1021/om049360b | ||||||||||||
Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||||
ID Code: | 79398 | ||||||||||||
Collection: | CaltechAUTHORS | ||||||||||||
Deposited By: | Ruth Sustaita | ||||||||||||
Deposited On: | 26 Jul 2017 16:23 | ||||||||||||
Last Modified: | 15 Nov 2021 17:47 |
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