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Insights into the Deactivation of Neutral Nickel Ethylene Polymerization Catalysts in the Presence of Functionalized Olefins

Waltman, Andrew W. and Younkin, Todd R. and Grubbs, Robert H. (2004) Insights into the Deactivation of Neutral Nickel Ethylene Polymerization Catalysts in the Presence of Functionalized Olefins. Organometallics, 23 (22). pp. 5121-5123. ISSN 0276-7333. doi:10.1021/om049360b. https://resolver.caltech.edu/CaltechAUTHORS:20170726-091441043

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Abstract

A study on the products of reaction between a neutral nickel(II) olefin polymerization catalyst and methyl acrylate is presented. A deactivation mechanism involving hydrogen transfer from substrate to catalyst is suggested.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/om049360bDOIArticle
http://pubs.acs.org/doi/abs/10.1021/om049360bPublisherArticle
http://pubs.acs.org/doi/suppl/10.1021/om049360bPublisherSupporting Information
ORCID:
AuthorORCID
Grubbs, Robert H.0000-0002-0057-7817
Additional Information:© 2004 American Chemical Society. Received 18 August 2004. Published online 29 September 2004. Published in print 1 October 2004. We thank the Rohm and Haas Corp. for funding, Dr. Mona Shahgholi for mass spectral analysis, and Jonathan Owen and Raissa Trend for helpful discussions.
Funders:
Funding AgencyGrant Number
Rohm and Haas CorporationUNSPECIFIED
Issue or Number:22
DOI:10.1021/om049360b
Record Number:CaltechAUTHORS:20170726-091441043
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20170726-091441043
Official Citation:Insights into the Deactivation of Neutral Nickel Ethylene Polymerization Catalysts in the Presence of Functionalized Olefins Andrew W. Waltman, Todd R. Younkin, and Robert H. Grubbs Organometallics 2004 23 (22), 5121-5123 DOI: 10.1021/om049360b
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:79398
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:26 Jul 2017 16:23
Last Modified:15 Nov 2021 17:47

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