A Versatile Precursor for the Synthesis of New Ruthenium Olefin Metathesis Catalysts

Sanford, Melanie S. and Love, Jennifer A. and Grubbs, Robert H. (2001) A Versatile Precursor for the Synthesis of New Ruthenium Olefin Metathesis Catalysts. Organometallics, 20 (25). pp. 5314-5318. ISSN 0276-7333. https://resolver.caltech.edu/CaltechAUTHORS:20170808-091344080

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Abstract

The ruthenium complex (IMesH_2)(Cl)_2(C_5H_5N)_2Ru═CHPh [IMesH_2 = 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene] (3) was prepared by the reaction of (IMesH_2)(PCy_3)(Cl)_2Ru═CHPh (2) with an excess of pyridine. Complex 3 contains substitutionally labile pyridine and chloride ligands and serves as a versatile starting material for the synthesis of new ruthenium benzylidenes.

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Article

Related URLs:

URL	URL Type	Description
http://dx.doi.org/10.1021/om010599r	DOI	Article
http://pubs.acs.org/doi/abs/10.1021/om010599r	Publisher	Article
http://pubs.acs.org/doi/suppl/10.1021/om010599r	Publisher	Supporting Information

ORCID:

Author	ORCID
Sanford, Melanie S.	0000-0001-9342-9436
Love, Jennifer A.	0000-0003-2373-1036
Grubbs, Robert H.	0000-0002-0057-7817

Additional Information:

© 2001 American Chemical Society. Received 5 July 2001. Published online 3 November 2001. Published in print 1 December 2001. Lawrence Henling and Michael Day are acknowledged for the X-ray crystallographic study described herein. The authors would like to thank the NSF for generous funding of this research. J.A.L. thanks the NIH for a postdoctoral fellowship.

Funders:

Funding Agency	Grant Number
NSF	UNSPECIFIED
NIH Postdoctoral Fellowship	UNSPECIFIED

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CaltechAUTHORS:20170808-091344080

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https://resolver.caltech.edu/CaltechAUTHORS:20170808-091344080

Official Citation:

A Versatile Precursor for the Synthesis of New Ruthenium Olefin Metathesis Catalysts Melanie S. Sanford, Jennifer A. Love, and Robert H. Grubbs Organometallics 2001 20 (25), 5314-5318 DOI: 10.1021/om010599r

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79914

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CaltechAUTHORS

Deposited By:

Ruth Sustaita

Deposited On:

09 Aug 2017 20:35

Last Modified:

03 Oct 2019 18:25

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