Sanford, Melanie S. and Love, Jennifer A. and Grubbs, Robert H. (2001) A Versatile Precursor for the Synthesis of New Ruthenium Olefin Metathesis Catalysts. Organometallics, 20 (25). pp. 5314-5318. ISSN 0276-7333. https://resolver.caltech.edu/CaltechAUTHORS:20170808-091344080
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Abstract
The ruthenium complex (IMesH_2)(Cl)_2(C_5H_5N)_2Ru═CHPh [IMesH_2 = 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene] (3) was prepared by the reaction of (IMesH_2)(PCy_3)(Cl)_2Ru═CHPh (2) with an excess of pyridine. Complex 3 contains substitutionally labile pyridine and chloride ligands and serves as a versatile starting material for the synthesis of new ruthenium benzylidenes.
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Additional Information: | © 2001 American Chemical Society. Received 5 July 2001. Published online 3 November 2001. Published in print 1 December 2001. Lawrence Henling and Michael Day are acknowledged for the X-ray crystallographic study described herein. The authors would like to thank the NSF for generous funding of this research. J.A.L. thanks the NIH for a postdoctoral fellowship. | ||||||||||||
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Issue or Number: | 25 | ||||||||||||
Record Number: | CaltechAUTHORS:20170808-091344080 | ||||||||||||
Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20170808-091344080 | ||||||||||||
Official Citation: | A Versatile Precursor for the Synthesis of New Ruthenium Olefin Metathesis Catalysts Melanie S. Sanford, Jennifer A. Love, and Robert H. Grubbs Organometallics 2001 20 (25), 5314-5318 DOI: 10.1021/om010599r | ||||||||||||
Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||||
ID Code: | 79914 | ||||||||||||
Collection: | CaltechAUTHORS | ||||||||||||
Deposited By: | Ruth Sustaita | ||||||||||||
Deposited On: | 09 Aug 2017 20:35 | ||||||||||||
Last Modified: | 03 Oct 2019 18:25 |
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