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A Versatile Precursor for the Synthesis of New Ruthenium Olefin Metathesis Catalysts

Sanford, Melanie S. and Love, Jennifer A. and Grubbs, Robert H. (2001) A Versatile Precursor for the Synthesis of New Ruthenium Olefin Metathesis Catalysts. Organometallics, 20 (25). pp. 5314-5318. ISSN 0276-7333. https://resolver.caltech.edu/CaltechAUTHORS:20170808-091344080

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Abstract

The ruthenium complex (IMesH_2)(Cl)_2(C_5H_5N)_2Ru═CHPh [IMesH_2 = 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene] (3) was prepared by the reaction of (IMesH_2)(PCy_3)(Cl)_2Ru═CHPh (2) with an excess of pyridine. Complex 3 contains substitutionally labile pyridine and chloride ligands and serves as a versatile starting material for the synthesis of new ruthenium benzylidenes.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/om010599rDOIArticle
http://pubs.acs.org/doi/abs/10.1021/om010599rPublisherArticle
http://pubs.acs.org/doi/suppl/10.1021/om010599rPublisherSupporting Information
ORCID:
AuthorORCID
Sanford, Melanie S.0000-0001-9342-9436
Love, Jennifer A.0000-0003-2373-1036
Grubbs, Robert H.0000-0002-0057-7817
Additional Information:© 2001 American Chemical Society. Received 5 July 2001. Published online 3 November 2001. Published in print 1 December 2001. Lawrence Henling and Michael Day are acknowledged for the X-ray crystallographic study described herein. The authors would like to thank the NSF for generous funding of this research. J.A.L. thanks the NIH for a postdoctoral fellowship.
Funders:
Funding AgencyGrant Number
NSFUNSPECIFIED
NIH Postdoctoral FellowshipUNSPECIFIED
Issue or Number:25
Record Number:CaltechAUTHORS:20170808-091344080
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20170808-091344080
Official Citation:A Versatile Precursor for the Synthesis of New Ruthenium Olefin Metathesis Catalysts Melanie S. Sanford, Jennifer A. Love, and Robert H. Grubbs Organometallics 2001 20 (25), 5314-5318 DOI: 10.1021/om010599r
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:79914
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:09 Aug 2017 20:35
Last Modified:03 Oct 2019 18:25

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