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Bond-stretch isomerism: a case study of a quiet controversy

Labinger, Jay A. (2002) Bond-stretch isomerism: a case study of a quiet controversy. Comptes Rendus Chimie, 5 (4). pp. 235-244. ISSN 1631-0748. doi:10.1016/S1631-0748(02)01380-2. https://resolver.caltech.edu/CaltechAUTHORS:20170824-102457732

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Abstract

The phenomenon of bond-stretch isomerism in transition metal coordination chemistry – two isomers of a complex differing only in one bond length – was first suggested in the early 1970s and remained controversial until the early 1990s, when it was generally agreed to be illusory. The course of this controversy is considered from two points of view, as a straightforward narrative in chemical history, and in the context of several concepts promulgated by studies of science from the outside.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1016/S1631-0748(02)01380-2DOIArticle
http://www.sciencedirect.com/science/article/pii/S1631074802013802PublisherArticle
ORCID:
AuthorORCID
Labinger, Jay A.0000-0002-1942-9232
Additional Information:© 2002 Académie des sciences / Éditions scientifiques et médicales Elsevier SAS. Received 8 March 2002, Accepted 25 April 2002, Available online 27 June 2002. I am indebted to John Enemark, Vern Gibson, Barry Haymore, Roald Hoffmann, Ged Parkin, Karl Wieghardt, Mike Hall and Jeremy Burdett for extensive discussions and/or providing reminiscences and documents.
Subject Keywords:scientific controversy; isomerism; crystallography
Issue or Number:4
DOI:10.1016/S1631-0748(02)01380-2
Record Number:CaltechAUTHORS:20170824-102457732
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20170824-102457732
Official Citation:Jay A. Labinger, Bond-stretch isomerism: a case study of a quiet controversy, Comptes Rendus Chimie, Volume 5, Issue 4, 2002, Pages 235-244, ISSN 1631-0748, http://dx.doi.org/10.1016/S1631-0748(02)01380-2. (http://www.sciencedirect.com/science/article/pii/S1631074802013802)
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:80767
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:24 Aug 2017 23:18
Last Modified:15 Nov 2021 19:38

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