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Synthesis and evaluation of dithiolate-modified ruthenium olefin metathesis catalysts

Montgomery, Timothy and Grubbs, Robert (2017) Synthesis and evaluation of dithiolate-modified ruthenium olefin metathesis catalysts. In: 254th American Chemical Society National Meeting & Exposition, August 20-24, 2017, Washington, DC.

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A premier method for the formation of carbon-carbon double bonds, olefin metathesis has found widespread use in synthetic org., biol., and materials chem. Recent advancements made using ruthenium olefin metathesis catalysts have employed dithiolate X-type ligands, giving rise to a kinetically (E)-selective olefin metathesis process through stereoretention of the starting olefin geometry. Modification of the dithiolate ligands provides a path to metathesis catalysts contg. interesting electronic and stereochem. properties. These catalysts deliver a better understanding of the structure-activity relationships obsd. in olefin metathesis catalysts.

Item Type:Conference or Workshop Item (Paper)
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URLURL TypeDescription Website
Montgomery, Timothy0000-0003-0975-088X
Grubbs, Robert0000-0002-0057-7817
Additional Information:© 2017 American Chemical Society.
Record Number:CaltechAUTHORS:20170915-080632926
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Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:81477
Deposited By: Tony Diaz
Deposited On:15 Sep 2017 16:34
Last Modified:03 Oct 2019 18:43

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