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A Model for the Structure of the Large-Pore Zeolite SSZ-31

Lobo, Raul F. and Tsapatsis, Michael and Freyhardt, Clemens C. and Chan, Ignatius and Chen, Cong-Yan and Zones, Stacey I. and Davis, Mark E. (1997) A Model for the Structure of the Large-Pore Zeolite SSZ-31. Journal of the American Chemical Society, 119 (16). pp. 3732-3744. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20170920-102018890

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Abstract

A model for the structure of the zeolite SSZ-31 is presented. The model is obtained by combining information from adsorption capacity measurements, transmission electron microscopy, and high-resolution X-ray diffraction. SSZ-31 is a one-dimensional large-pore zeolite with a framework density of 18.7 tetrahedral(T)-atoms per nm^(-3) and a bulk density of 1.87 g cm^(-3). The pore apertures are elliptical with major and minor axes of approximately 8.6 Å × 5.7 Å. SSZ-31 is an extreme example of a complex and highly faulted zeolite. The structure can be described as an intergrowth of four different but structurally related polymorphs.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1021/ja963925gDOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja963925gPublisherArticle
http://pubs.acs.org/doi/suppl/10.1021/ja963925gPublisherSupporting Information
ORCID:
AuthorORCID
Tsapatsis, Michael0000-0001-5610-3525
Davis, Mark E.0000-0001-8294-1477
Additional Information:© 1997 American Chemical Society. Received November 12, 1996. Publication Date (Web): April 23, 1997. We thank P. Wagner (CIT) who helped to obtain several of the in-house XRD patterns of SSZ-31 and Y. Nakagawa and L. T. Yuen (Chevron) for the synthesis of several of the samples of SSZ-31 used in this work. R. C. Medrud (Chevron) helped to obtain the synchrotron XRD pattern of SSZ-31. We acknowledge D. E. Cox for assistance in collecting the synchrotron data. The XRD data were collected at X7A beam line, National Synchrotron Light Source, Brookhaven National Laboratory, which is supported by the Department of Energy, Division of Materials Sciences and Division of Chemical Sciences. R.F.L. is grateful to the University of Delaware Research Foundation and to Chevron Research and Technology for financial support. M.T. is grateful to the David and Lucile Packard Foundation for a Fellowship in Science and Engineering and to the National Center for Electron Mcroscopy for a NCEM/DOE Fellowship. We thank the W. M. Keck Polymer Morphology Laboratory for use of EM facilities.
Funders:
Funding AgencyGrant Number
Department of Energy (DOE)UNSPECIFIED
University of DelawareUNSPECIFIED
Chevron Research and Technology Co.UNSPECIFIED
David and Lucile Packard FoundationUNSPECIFIED
National Center for Electron McroscopyUNSPECIFIED
Issue or Number:16
Record Number:CaltechAUTHORS:20170920-102018890
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20170920-102018890
Official Citation:A Model for the Structure of the Large-Pore Zeolite SSZ-31. Raul F. Lobo, Michael Tsapatsis, Clemens C. Freyhardt, Ignatius Chan, Cong-Yan Chen, Stacey I. Zones, and Mark E. Davis. Journal of the American Chemical Society 1997 119 (16), 3732-3744. DOI: 10.1021/ja963925g
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:81614
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:20 Sep 2017 18:15
Last Modified:09 Mar 2020 13:19

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