Takematsu, Kana and Wehlin, Sara A. M. and Sattler, Wesley and Winkler, Jay R. and Gray, Harry B. (2017) Two-photon spectroscopy of tungsten(0) arylisocyanides using nanosecond-pulsed excitation. Dalton Transactions, 46 (39). pp. 13188-13193. ISSN 1477-9226. doi:10.1039/c7dt02632c. https://resolver.caltech.edu/CaltechAUTHORS:20170921-104309376
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Abstract
The two-photon absorption (TPA) cross sections (δ) for tungsten(0) arylisocyanides (W(CNAr)6) were determined in the 800–1000 nm region using two-photon luminescence (TPL) spectroscopy. The complexes have high TPA cross sections, in the range 1000–2000 GM at 811.8 nm. In comparison, the cross section at 811.8 nm for tris-(2,2′-bipyridine)ruthenium(II), [Ru(bpy)_3]^(2+), is 7 GM. All measurements were performed using a nanosecond-pulsed laser system.
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| Additional Information: | © 2017 The Royal Society of Chemistry. The article was received on 19 Jul 2017, accepted on 11 Sep 2017 and first published on 21 Sep 2017. Research was supported by CCI Solar Fuels (NSF CHE-1305124) and the Arnold and Mabel Beckman Foundation. There are no conflicts to declare. | ||||||||||
| Group: | CCI Solar Fuels | ||||||||||
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| Issue or Number: | 39 | ||||||||||
| DOI: | 10.1039/c7dt02632c | ||||||||||
| Record Number: | CaltechAUTHORS:20170921-104309376 | ||||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20170921-104309376 | ||||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||
| ID Code: | 81675 | ||||||||||
| Collection: | CaltechAUTHORS | ||||||||||
| Deposited By: | Tony Diaz | ||||||||||
| Deposited On: | 21 Sep 2017 18:02 | ||||||||||
| Last Modified: | 15 Nov 2021 19:45 |
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