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Oxidation chemistry of d^0 organometallic complexes

Burk, Mark J. and Tumas, William and Ward, Michael D. and Wheeler, David R. (1990) Oxidation chemistry of d^0 organometallic complexes. Journal of the American Chemical Society, 112 (16). pp. 6133-6135. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20171107-084406057

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Abstract

Electron-transfer processes can play an important role in organometallic chemistry. Herein, we demonstrate that even d^0 organometallic complexes exhibit a rich redox chemistry and present electrochemical, kinetics, and stereochemical studies that establish a general outer-sphere oxidation process for d^0 group 4 metallocene complexes. This oxidation chemistry closely parallels the reported LMCT photochemistry of these complexes.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1021/ja00172a042DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja00172a042PublisherArticle
http://pubs.acs.org/doi/suppl/10.1021/ja00172a042PublisherSupporting Information
Additional Information:© 1990 American Chemical Society. Received February 26, 1990. We are grateful to E. J. Delawski, J. E. Feaster, B. A. Kurtz, and J. A. Suriano for expert technical assistance.
Issue or Number:16
Record Number:CaltechAUTHORS:20171107-084406057
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20171107-084406057
Official Citation:Oxidation chemistry of d0 organometallic complexes. Mark J. Burk, William Tumas, Michael D. Ward, and David R. Wheeler. Journal of the American Chemical Society 1990 112 (16), 6133-6135. DOI: 10.1021/ja00172a042
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:83022
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:07 Nov 2017 18:24
Last Modified:03 Oct 2019 19:01

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