Burk, Mark J. and Tumas, William and Ward, Michael D. and Wheeler, David R. (1990) Oxidation chemistry of d^0 organometallic complexes. Journal of the American Chemical Society, 112 (16). pp. 6133-6135. ISSN 0002-7863. doi:10.1021/ja00172a042. https://resolver.caltech.edu/CaltechAUTHORS:20171107-084406057
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Abstract
Electron-transfer processes can play an important role in organometallic chemistry. Herein, we demonstrate that even d^0 organometallic complexes exhibit a rich redox chemistry and present electrochemical, kinetics, and stereochemical studies that establish a general outer-sphere oxidation process for d^0 group 4 metallocene complexes. This oxidation chemistry closely parallels the reported LMCT photochemistry of these complexes.
Item Type: | Article | ||||||||||||
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Additional Information: | © 1990 American Chemical Society. Received February 26, 1990. We are grateful to E. J. Delawski, J. E. Feaster, B. A. Kurtz, and J. A. Suriano for expert technical assistance. | ||||||||||||
Issue or Number: | 16 | ||||||||||||
DOI: | 10.1021/ja00172a042 | ||||||||||||
Record Number: | CaltechAUTHORS:20171107-084406057 | ||||||||||||
Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20171107-084406057 | ||||||||||||
Official Citation: | Oxidation chemistry of d0 organometallic complexes. Mark J. Burk, William Tumas, Michael D. Ward, and David R. Wheeler. Journal of the American Chemical Society 1990 112 (16), 6133-6135. DOI: 10.1021/ja00172a042 | ||||||||||||
Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||||
ID Code: | 83022 | ||||||||||||
Collection: | CaltechAUTHORS | ||||||||||||
Deposited By: | Tony Diaz | ||||||||||||
Deposited On: | 07 Nov 2017 18:24 | ||||||||||||
Last Modified: | 15 Nov 2021 19:54 |
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