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Oxidation chemistry of d^0 organometallic complexes

Burk, Mark J. and Tumas, William and Ward, Michael D. and Wheeler, David R. (1990) Oxidation chemistry of d^0 organometallic complexes. Journal of the American Chemical Society, 112 (16). pp. 6133-6135. ISSN 0002-7863. doi:10.1021/ja00172a042.

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Electron-transfer processes can play an important role in organometallic chemistry. Herein, we demonstrate that even d^0 organometallic complexes exhibit a rich redox chemistry and present electrochemical, kinetics, and stereochemical studies that establish a general outer-sphere oxidation process for d^0 group 4 metallocene complexes. This oxidation chemistry closely parallels the reported LMCT photochemistry of these complexes.

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Additional Information:© 1990 American Chemical Society. Received February 26, 1990. We are grateful to E. J. Delawski, J. E. Feaster, B. A. Kurtz, and J. A. Suriano for expert technical assistance.
Issue or Number:16
Record Number:CaltechAUTHORS:20171107-084406057
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Official Citation:Oxidation chemistry of d0 organometallic complexes. Mark J. Burk, William Tumas, Michael D. Ward, and David R. Wheeler. Journal of the American Chemical Society 1990 112 (16), 6133-6135. DOI: 10.1021/ja00172a042
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:83022
Deposited By: Tony Diaz
Deposited On:07 Nov 2017 18:24
Last Modified:15 Nov 2021 19:54

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