Oxidation chemistry of d^0 organometallic complexes

Burk, Mark J. and Tumas, William and Ward, Michael D. and Wheeler, David R. (1990) Oxidation chemistry of d^0 organometallic complexes. Journal of the American Chemical Society, 112 (16). pp. 6133-6135. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20171107-084406057

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Abstract

Electron-transfer processes can play an important role in organometallic chemistry. Herein, we demonstrate that even d^0 organometallic complexes exhibit a rich redox chemistry and present electrochemical, kinetics, and stereochemical studies that establish a general outer-sphere oxidation process for d^0 group 4 metallocene complexes. This oxidation chemistry closely parallels the reported LMCT photochemistry of these complexes.

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Article

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URL	URL Type	Description
https://doi.org/10.1021/ja00172a042	DOI	Article
http://pubs.acs.org/doi/abs/10.1021/ja00172a042	Publisher	Article
http://pubs.acs.org/doi/suppl/10.1021/ja00172a042	Publisher	Supporting Information

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CaltechAUTHORS:20171107-084406057

Persistent URL:

https://resolver.caltech.edu/CaltechAUTHORS:20171107-084406057

Official Citation:

Oxidation chemistry of d0 organometallic complexes. Mark J. Burk, William Tumas, Michael D. Ward, and David R. Wheeler. Journal of the American Chemical Society 1990 112 (16), 6133-6135. DOI: 10.1021/ja00172a042

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83022

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CaltechAUTHORS

Deposited By:

Tony Diaz

Deposited On:

07 Nov 2017 18:24

Last Modified:

03 Oct 2019 19:01

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